Unprecedented Stereoselectivity in the Addition of Organoiron(II) Reagents to Cyclohaxanone Derivatives

DOI: 10.1039/c39930000328

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 328 - 330 (1993)

Update date:2022-08-17

Topics:

Authors:

Reetz, Manfred T.

Stanchev, Stephan

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39930000328

Various organoiron(II) reagents undergo Grignard-type additions to substituted cyclohexanone derivatives, C-C bond formation occurring stereoselectively from the equatorial direction (97 - 100percent selectivity).

Full text of DOI:10.1039/c39930000328

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:cis-1,3-dimethylcyclohexanol

Cas No:114221-86-2

R&D Labs maybe for 114221-86-2

Evergreen Chemical Industry Ltd.

Contact:86-553-4918210

Address:6#2-602 Wanhaobailing
Fusilin chemical science & technology co., ltd.

Contact:532-80698166/86057573, +86-400-669-7885

Address:School of Material Science & Engineering, Shandong Uinversity of Science & Technology, Huangdao Zone, Qindao, Shandong
Beijing ZhongDaXinHe Chemical Product Co.,Ltd(expird)

Contact:010-52876516

Address:tongzhoubeiyuan
Jiangsu Jiuri Chemical Co.,Ltd.

Contact:+86-519-82118868

Address:Tianwang Town, Jurong City, Jiangsu Province, China
Jiaxing Carry Bio-Chem Technology Co.,Ltd

website:http://www.carrybiotech.com

Contact:0573-82788958

Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China

Relevant to this article

Biomimetic catalytic system driven by electron transfer for selective oxygenation of hydrocarbon

Doi:10.1021/ja047297b
(2004)
Labdane diterpenes and flavonoids from Leonurus japonicus

Doi:10.1002/hlca.201000043
(2010)
Anti-cancer potential of novel glycosylated 1,4-substituted triazolylchalcone derivatives

Doi:10.1016/j.bmcl.2019.08.019
(2019)
Electron-Density Distribution in Crystals of Dipotassium Tetrachloropalladate(II) and Dipotassium Hexachloropalladate(IV), K2 and K2 at 120 K

Doi:10.1107/S0108768188010031
(1988)
Total Synthesis of Analogs of Topostin B, A DNA Topoisomerase I Inhibitor. Part 1. Synthesis of Fragments of Topostin B-1 Analogs

Doi:10.1016/0040-4020(95)00616-G
(1995)
Attemted Functionalisation of a Mononuclear Barium Complex of a 24-Membered Bibracchial Tetraimine Schiff-base Macrocycle derived from Tris(2-aminoethyl)amine using Salicylaldehyde

Doi:10.1039/DT9950000765
(1995)

Article Doi