
Tetrahedron Letters p. 2127 - 2130 (1986)
Update date:2022-08-28
Topics:
Miyashita, Akira
Ishida, Jun-ya
Nohira, Hiroyuki
1-Metalla-2-oxacyclobutane complex, which was formed by intramolecular γ-hydrogen elimination of alkoxy(alkyl)metal complex of Ni or Pd, yields mainly oxirane, while its Ti complex affords olefins resulting from C-O bond cleavage.
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(1960)