Synthesis and characterization of sym-cis- and unsym-cis-(ethylenediamine-N,N'-di-3-propionato)cobalt(III) complexes with symmetrical N,N'-substituted diamines

Article abstract of DOI:10.1080/00945719909351719

A series of octahedral sym-cis and unsym-cis cobalt(III) complexes involving tetradentate ethylenediamine-N,N'-di-3-propionate ion (eddp) and symmetrical diamines, [ethylenediamine (en), N,N'-dimethylethylenediamine (dmen) and N,N'-diethylethylenediamine (deen)] were prepared by reaction of sodium unsym-cis-(ethylenediamine-N,N'-di-3-propionato)(carbonato)cobalt-ate(III) dihydrate with the corresponding diamine. The stereochemistry of the complexes prepared was investigated through ion-exchange chromatography, electronic absorption, infrared and ¹H NMR spectroscopy.

Full text of DOI:10.1080/00945719909351719

Synthesis and Reactivity in Inorganic and Metal-Organic
Chemistry
ISSN: 0094-5714 (Print) 1532-2440 (Online) Journal homepage: http://www.tandfonline.com/loi/lsrt19
Synthesis and Characterization of Sym-Cis-
and Unsym-Cis-(Ethylenediamine-N, N′-Di-3-
Propionato)Cobalt(Iii) Complexes with Symmetrical
N, N′-Substituted Diamines
Sanja R. Grguric & Tibor J. Sabo
To cite this article: Sanja R. Grguric & Tibor J. Sabo (1999) Synthesis and Characterization of
Sym-Cis- and Unsym-Cis-(Ethylenediamine-N, N′-Di-3-Propionato)Cobalt(Iii) Complexes with
Symmetrical N, N′-Substituted Diamines, Synthesis and Reactivity in Inorganic and Metal-
Organic Chemistry, 29:9, 1567-1578, DOI: 10.1080/00945719909351719
To link to this article: http://dx.doi.org/10.1080/00945719909351719
Published online: 23 Apr 2008.
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Date: 14 June 2016, At: 14:48