Photochemically induced coupling reaction of triarylstibines with olefins

DOI: 10.1016/S0040-4039(98)02281-3

Source and publish data:

Tetrahedron Letters p. 9743 - 9746 (1998)

Update date:2022-08-29

Topics:

Authors:

Kakusawa, Naoki

Tsuchiya, Takashi

Kurita, Jyoji

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Article abstract of DOI:10.1016/S0040-4039(98)02281-3

Photoreaction of triarylstibines with styrenes resulted in the formation of 2-aryl-1-phenylethanols accompanied by air oxidation. Formation of the products has been explained by the valence expansion of the oxygen-antimony- styrene complex to a five-valent intermediate, followed by reductive coupling.

Full text of DOI:10.1016/S0040-4039(98)02281-3

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