Tetrahedron Letters p. 9743 - 9746 (1998)
Update date:2022-08-29
Topics:
Kakusawa, Naoki
Tsuchiya, Takashi
Kurita, Jyoji
Photoreaction of triarylstibines with styrenes resulted in the formation of 2-aryl-1-phenylethanols accompanied by air oxidation. Formation of the products has been explained by the valence expansion of the oxygen-antimony- styrene complex to a five-valent intermediate, followed by reductive coupling.
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