Journal of Organometallic Chemistry p. 65 - 70 (1982)
Update date:2022-08-31
Topics:
Bianchi, Mario
Matteoli, Ugo
Menchi, Gloria
Frediani, Piero
Piacenti, Franco
Disproportionation of aldehydes with formation of the corresponding acid and alcohol is catalyzed by phosphine-substituted cluster ruthenium carbonyls.The reaction takes place in the presence of water.An enantiomeric selection is shown by H4Ru4(CO)8<(-)-DIOP>2 in the disproportionation reaction of (R)(S)-2-methylbutanal; (-)(S)-2-methylbutanoic acid of 1.7percent optical purity is obtained.
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