Journal of the Chemical Society. Perkin transactions I p. 1315 - 1317 (1996)
Update date:2022-08-10
Topics:
Entwistle, David A.
Jordan, Stuart I.
Montgomery, John
Pattenden, Gerald
A total synthesis of the virginiamycin 14,15-anhydropristinamycin IIB 16 has been achieved from chiral, non-racemic starting materials, and using a route which features an intramolecular Stille coupling reaction, viz. 14→15, as the key stratagem. The virginiamycin 16 was identical with an authentic sample produced from a Streptomyces fermentation process.
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