A Novel and Efficient Route to Chiral A-Ring Aromatic Trichothecanes - The First Enantiocontrolled Total Synthesis of (-)-Debromofiliformin and (-)-Filiformin

DOI: 10.1016/0040-4020(95)00226-X

Source and publish data:

Tetrahedron p. 5511 - 5522 (1995)

Update date:2022-08-10

Topics:

Authors:

Nemoto, Hideo

Miyata, Junji

Hakamata, Hideki

Nagamochi, Masatoshi

Fukumoto, Keiichiro

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Article abstract of DOI:10.1016/0040-4020(95)00226-X

The first examples of asymmetric dihydroxylation (AD) of the cyclopropylidene derivatives 12a-e followed by enantiospecific 1,2-rearrangement of the resulted diols 13a-e to give the optically active cyclobutanones 15a-d and 11, and also the first enantioc

Full text of DOI:10.1016/0040-4020(95)00226-X

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