Diastereoselective bromodifluoromethylation of chiral imide enolates via insertion of difluorocarbene

DOI: 10.1016/0040-4039(95)00660-5

Source and publish data:

Tetrahedron Letters p. 3711 - 3714 (1995)

Update date:2022-08-22

Topics:

Authors:

Iseki, Katsuhiko

Asada, Daisuke

Takahashi, Mie

Nagai, Takabumi

Kobayashi, Yoshiro

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)00660-5

The bromodifluoromethylation of lithium enolates of chiral N-acyloxazolidinones via the insertion of difluorocarbene proceeds with good diastereomeric excess (68-92% de).

Full text of DOI:10.1016/0040-4039(95)00660-5

Products guided by the article

Product name:(4S)-4-benzyl-3-(2-bromopropanoyl)oxazolidin-2-one

Cas No:192864-91-8

R&D Labs maybe for 192864-91-8

Beijing Century Richap Chemistry Co.,Ltd

Contact:+86- 010-64455497

Address:Guannan County, Lianyungang City, Jiangsu Province, China
Xinyanhe Pharmatech Co.,Ltd

Contact:+86-519-8525-2752

Address:Changzhou
Hangzhou yi lu biont technology Co., LTD

Contact:+86-571-88152630

Address:Hangzhoushi HuafengRoad Yicheng3Building1001room.
Cartoon Ingredients Co., Ltd

website:http://www.cartoonchem.com/

Contact:+86-25-58074918

Address:Room 2109, RuiHua Business Center,315 South ZhongShan Road, Nanjing 210001, China
Suzhou Zhonghelong Chemical Tech Co., Ltd【License cancellation】

Contact:+86 571-12345678

Address:Dunhuang Road, Suzhou Industrial Park, No.128 building 701 room Mansion

Relevant to this article

Metalloporphyrins immobilized on core-shell CeO₂@SiO₂ nanoparticles prepared by a double-coating method for oxidation of diphenyl methane

Doi:10.1016/j.apcata.2011.10.040
(2012)
Dynamics and crystal chemistry of tellurites. II. Composition- and temperature-dependence of the Raman spectra of x(Tl₂O) + (1 - x) Te₂O glasses: Evidence for a phase separation?

Doi:10.1016/j.jpcs.2003.11.020
(2004)
Doi:10.1016/0020-1650(68)90006-8
(1968)
Doi:10.1016/S0003-2670(00)88136-2
(1970)
Synthesis and characterization of linear, homopolyester, benzoyl-protected Bis-MPA

Doi:10.1021/acs.macromol.0c01045
(2020)
Activation of Chlorinated Methanes at the Surface of Nanoscopic Lewis Acidic Aluminum Fluorides

Doi:10.1002/cctc.201601238
(2017)

Article Doi