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Studies of Pendant-arm Macrocyclic Ligands. Part 5. Synthesis of Two Pyridine-containing Penta-aza Macrocycles with Single Pyrrolidinyl Pendant Arms and Characterisation of their Nickel(II) and Copper(II) Complexes. Crystal Structure of Perchlorato-3,7,...

DOI: 10.1039/DT9870000545

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 545 - 550 (1987)

Update date:2022-08-29

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Authors:

Alcock, Nathaniel W.Alcock, Nathaniel W.

Balakrishnan, Karappulli P.Balakrishnan, Karappulli P.

Moore, PeterMoore, Peter

Omar, Hadi A. A.Omar, Hadi A. A.

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Article abstract of DOI:10.1039/DT9870000545

Two new pyridine-containing penta-aza macrocyclic ligands, 7-<2'-(1''-pyrrolidinyl)ethyl>- and 7-<3'-(1''-pyrrolidinyl)propyl>-3,7,11,17-tetra-azabicyclo<11.3.1>heptadeca-1(17),13,15-triene (L1 and L2 respectively) have been prepared, and their nickel(II) and copper(II) complexes of formulae 1)(OClO3)> and 3 (M = Ni or Cu, L = L1 or L2) have been isolated and characterised.In the octahedral complex 1)(OClO3)> the presence of a co-ordinated perchlorate group has been established by X-ray crystallography, and the macrocyclic ligand found to co-ordinate close to the corners of a square pyramid with the pendant pyrrolidinyl group at the apical position.

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