A UNIQUE AND HIGHLY REMARKABLE BORON TRIFLUORIDE CATALYZED REARRANGEMENT OF 2,2-DI-t-BUTYLOXIRANE INTO 2,2,3,3,4,4-HEXAMETHYLTETRAHYDROFURAN

DOI: 10.1016/0040-4020(84)85013-9

Source and publish data:

Tetrahedron p. 3291 - 3294 (1984)

Update date:2022-08-10

Topics:

Authors:

Kimpe, Norbert De

Buyck, Laurent De

Verhe, Roland

Schamp, Niceas

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4020(84)85013-9

The boron trifluoride catalyzed rearrangement of 2,2-di-t-butyloxirane, involving competitive reactions of transient carbenium ions, could be selectively directed towards either 2,2,3,3,4,4-hexamethyltetrahydrofuran or 2-t-butyl-2,3-dimethyl-3-buten-1-ol.Hydride shift to afford 2,2-di-t-butylacetaldehyde was only observed to a minor extent.

Full text of DOI:10.1016/0040-4020(84)85013-9

Products guided by the article

Product name:2,2,3,4-tetramethylpentan-3-ol

Cas No:29772-39-2

R&D Labs maybe for 29772-39-2

Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
Anhui Sholon New Material Technology Co., Ltd.

website:http://www.sholonchem.com

Contact:+86-550-5261666

Address:4/F Block B, Beijing Chemical Building.No.520 Tianrun Road ,Science & Education Town Wujin District, Changzhou City Jiangsu Province
Shanghai Synmedia Chemical Co., Ltd

Contact:+86-21-38681880

Address:6th Floor, 11A Building, No.528 Ruiqing Road, Heqing town, Pudong new district, Shanghai China
Jining tiansheng chemical co.,ltd.

Contact:+86-537-5158722

Address:ROOM 1011, BLOCK B, CUIDU INTERNATIOAL BUSINESS CENTER, JINING CITY, CHINA
Synasia Inc

Contact:17316303296

Address:240 Amboy Ave

Relevant to this article

Studies on synthesis, structural, luminescent and thermal properties of a new non-linear optical crystal: 4-amino-4H-1,2,4-triazol-1-ium-3-hydroxy-2,4,6-trinitrophenolate

Doi:10.1016/j.physb.2016.12.009
(2017)
Turn-on fluorescence sensor for mono- and di-phosphonic acid derivatives using anthracene-based diamidine and its detection of amidinium-phosphonate and amidinium formation

Doi:10.1016/j.tet.2017.12.011
(2018)
Analysis of conjugated bile acids in human biological fluids. Synthesis of hyodeoxycholic acid 3- and 6-glycosides and related compounds

Doi:10.1248/cpb.42.1479
(1994)
Nazarov reactions intercepted by (4 + 3) cycloadditions with oxygen-substituted dienes

Doi:10.1021/acs.joc.5b00914
(2015)
Photochemical reaction of ergosta-4,6,8(14),22-tetraen-3-one

Doi:10.1248/cpb.44.843
(1996)
Synergistic effect of Mo₂N and Pt for promoted selective hydrogenation of cinnamaldehyde over Pt-Mo₂N/SBA-15

Doi:10.1039/c5cy01654a
(2016)

Article Doi