Tetrahedron p. 3291 - 3294 (1984)
Update date:2022-08-10
Topics:
Kimpe, Norbert De
Buyck, Laurent De
Verhe, Roland
Schamp, Niceas
The boron trifluoride catalyzed rearrangement of 2,2-di-t-butyloxirane, involving competitive reactions of transient carbenium ions, could be selectively directed towards either 2,2,3,3,4,4-hexamethyltetrahydrofuran or 2-t-butyl-2,3-dimethyl-3-buten-1-ol.Hydride shift to afford 2,2-di-t-butylacetaldehyde was only observed to a minor extent.
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