Tetrahedron Letters p. 533 - 536 (1982)
Update date:2022-08-17
Topics:
Watanabe, Yoshihito
Iyanagi, Takashi
Qae, Shigeru
A kinetic study on enzymatic S-oxygenation of sulfoxides to sulfones was carried out by a reconstituted system with purified cytochrome P-450.A linear correlation observed between log(Vmax)'s and the one-electron oxidation potentials of sulfoxides suggests that the oxygenation of sulfoxides proceeds via one electron transfer process to the active "oxenoid" intermediate of the enzyme.
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