One-Electron Reductive Cleavage of the C-Cl Bond of ArCF2Cl: Convenient Route for the Synthesis of ArCF2 Derivatives

Article abstract of DOI:10.1246/bcsj.69.2019

When ArCF₂Cl was reacted with PhSeNa in DMF in the presence of light, it was found that a S_RN1 type reaction occurred to give ArCF₂SePh. As the reaction did not proceed without light, the substitution reaction should be in