Hetero Diels-Alder reaction of benzenesulfonyl cyanide with cyclopentadiene using chiral Lewis acids

DOI: 10.1248/cpb.44.850

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 850 - 852 (1996)

Update date:2022-08-16

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Authors:

Katagiri, Nobuya

Makino, Masashi

Tamura, Takahiro

Kaneko, Chikara

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Article abstract of DOI:10.1248/cpb.44.850

Asymmetric induction was observed in the hetero Diels-Alder reaction of benzenesulfonyl cyanide with cyclopentadiene using chiral Lewis acids. This is the first instance of asymmetric Diels-Alder reaction involving a sulfonyl group in the presence of a chiral Lewis acid.

Full text of DOI:10.1248/cpb.44.850

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