Chemistry Letters p. 623 - 626 (1980)
Update date:2022-08-23
Topics:
Tanaka, Katsumi
Miyahara, Koshiro
Tanaka, Ken-ichi
Co-isomerization of d0- and d8-cis-2-butene was carried out on a novel catalyst, MoOx/β-TiO2 (2.9>x>2.3), which is active for olefin metathesis reaction without inter- and intra-molecular hydrogen scrambling of olefins.The ratio, d4/(d0+d8), in produced trans-2-butene was found to be zero at the initial stage of the reaction, indicating a type of cis-trans isomerization by intra-molecular metathesis.
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