Pb2+/Pb0 redox equilibria in sodium borate, silicate, and aluminosilicate melts

Article abstract of DOI:10.1149/1.2097061

Pb²⁺/Pb⁰ redox equilibrium was studied with linear sweep voltammetry. The activity of PbO increases with the solvent basicity. A Pourbaix diagram analogue is presented with redox data obtained from the present and previous studies. The diffusivity of Pb²⁺ ion was evaluated from the peak currents and the effect of alumina upon it is discussed.

Full text of DOI:10.1149/1.2097061

Pb2+/Pb0 Redox Equilibria in Sodium Borate, Silicate,
and Aluminosilicate Melts
A. Sasahira, K. Kawamura, M. Shimizu, N. Takada, M. Hongo and T. Yokokawa
J. Electrochem. Soc. 1989, Volume 136, Issue 7, Pages 1861-1864.
doi: 10.1149/1.2097061
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