Tetrahedron Letters p. 4637 - 4640 (1984)
Update date:2022-08-25
Topics:
Evans, David A.
Morrissey, Michael M.
The present investigation documents the fact that hydroxyl-directed hydrogenation of cyclic and acyclic olefinic alcohols with the cationic iridium catalyst, Ir(COD)py(PCy3)PF6, exhibits reaction diastereoselectivity which is dependent upon catalyst-substrate stoichiometry.
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