HYDROXYL-DIRECTED OLEFIN HYDROGENATION WITH IRIDIUM CATALYSTS. THE DOCUMENTATION OF CATALYST : SUBSTRATE STOICHIOMETRY AS A VARIABLE IN REACTION DIASTEREOSELECTION.

DOI: 10.1016/S0040-4039(01)91220-1

Source and publish data:

Tetrahedron Letters p. 4637 - 4640 (1984)

Update date:2022-08-25

Topics:

Authors:

Evans, David A.

Morrissey, Michael M.

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Article abstract of DOI:10.1016/S0040-4039(01)91220-1

The present investigation documents the fact that hydroxyl-directed hydrogenation of cyclic and acyclic olefinic alcohols with the cationic iridium catalyst, Ir(COD)py(PCy3)PF6, exhibits reaction diastereoselectivity which is dependent upon catalyst-substrate stoichiometry.

Full text of DOI:10.1016/S0040-4039(01)91220-1

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