Journal of the Chemical Society. Perkin transactions II p. 1686 - 1689 (1980)
Update date:2022-08-11
Topics:
Clark, Timothy
Knox, Trevor McO.
McKervey, M. Anthony
Mackle, Henry
The enthalpies of combustion and of sublimation four mono-oxygenated diamantanes have been determined.The derived solid and gas-phase enthalpies of formation in kcal mol-1 at 298.15 K follow: diamantanone, -81.16+/-0.38, -56.53+/-0.41; diamantan-1-ol, -102.49+/-0.24, -74.30+/-0.28; diamantan-3-ol, -98.89+/-0.35, -71.14+/-1.10; diamantan-4-ol, -103.96+/-0.39, -75.80+/-0.39.Oxo and hydroxy group increments within the diamantane, adamantane, and cyclohexane series are discussed.Enthalpy differences betveen the isomeric diamantanols are compared with existing data from equilibration studies in solution.Comparisons are made between the experimental gas-phase enthalpies of formation and those obtained by molecular mechanics (empirical force field) calculations based on the Allinger MM1 force field model.
View MoreZibo Fuxi'er Chemical Co.,Ltd （Shanxian Fuxi'er Chemical Co.,Ltd）
Contact:+86-533-2091422
Address:Eastern 4 on the 3th Road ,Liangxiang Industrial Park, Zibo city ,Shandong,China
Ningxia Soochow Agrochemical Limited Company
Contact:(+86）0512 6320 8190
Address:wujiang
Shanghai SMEC Trading Co., Ltd.
website:http://www.shanghaismec.com
Contact:+86-21-68811293
Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Weifang Jahwa Chemical Co.,Ltd
Contact:0086-536-8897731,8897730
Address:No.5166 East Dongfeng Street,Weifang,Shandong,China
Wuhan Soleado Technology Co.,Ltd.
Contact:86-2783341481 18971291927
Address:RM2405 Unit 1 Builing 1, Taiyin Tower, Changqing Road,Wuhan China
Doi:10.1002/cssc.201601824
(2017)Doi:10.1039/b707844g
(2007)Doi:10.1021/acs.joc.9b00873
(2019)Doi:10.1016/j.jphotochem.2020.112780
(2020)Doi:10.1016/S0040-4039(01)00636-0
(2001)Doi:10.1111/j.1745-4549.2001.tb00446.x
(1911)
