Isolation of cis-dimethyl-(methoxycarbonyl)(triphenylphosphine)gold(III)

DOI: 10.1021/om00100a029

Source and publish data:

Organometallics p. 2238 - 2239 (1988)

Update date:2022-08-30

Topics:

Authors:

Komiya, Sanshiro

Ishikawa, Makoto

Ozaki, Satoshi

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Article abstract of DOI:10.1021/om00100a029

cis-Dimethyl(methoxycarbonyl)(triphenylphosphine)gold(III) (1) has been prepared by the reaction of carbon monoxide with a mixture of cis-dimethyliodo-(triphenylphosphine)gold(III) and sodium methoxide in methanol. Thermolysis of 1 results in the competitive reductive elimination of methyl acetate and ethane.

Full text of DOI:10.1021/om00100a029

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