14916-80-4 Usage
Chemical Properties
clear colorless to yellow liquid
Uses
Different sources of media describe the Uses of 14916-80-4 differently. You can refer to the following data:
1. 3-Octyn-1-ol, is used for a study of the reduction of acetylenic compounds, including this alcohol, to (E)-alkenes by alkali metals in liquid ammonia. Some other applications includes as corrosion inhibitor formulation, metal complex solution, solvent stabilizer, biodegradable chemical intermediate to make pharmaceuticals, chemical compound synthesis and reagents
2. 3-Octyn-1-ol may be used in the preparation of:(3Z)-octen-1-ol7-octyn-1-ol3-cis-octenoic acid
General Description
3-Octyn-1-ol is a homopropargylic alcohol that can be prepared from 3-butyn-1-ol and 1-bromobutane.
Check Digit Verification of cas no
The CAS Registry Mumber 14916-80-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,9,1 and 6 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 14916-80:
(7*1)+(6*4)+(5*9)+(4*1)+(3*6)+(2*8)+(1*0)=114
114 % 10 = 4
So 14916-80-4 is a valid CAS Registry Number.
InChI:InChI=1/C8H14O/c1-2-3-4-5-6-7-8-9/h9H,2-4,7-8H2,1H3
14916-80-4Relevant articles and documents
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Knight,Diamond
, p. 400,403 (1959)
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Disselnkoetter et al.
, p. 1591,1595 (1976)
Sustainable, mild and efficient p-methoxybenzyl ether deprotections utilizing catalytic DDQ
Walsh, Katie,Sneddon, Helen F.,Moody, Christopher J.
, p. 7380 - 7387 (2017/09/13)
A procedure for the selective deprotection of p-methoxybenzyl ethers using catalytic amounts of DDQ and of sodium nitrite, with oxygen as the terminal oxidant, is reported.
Enzyme-triggered enantioconvergent transformation of haloalkyl epoxides
Mayer, Sandra F.,Steinreiber, Andreas,Orru, Romano V. A.,Faber, Kurt
, p. 4537 - 4542 (2007/10/03)
Biocatalytic hydrolysis of 2,3-disubstituted rac-cis- and rac-trans-haloalkyl epoxides 1a-8a using the epoxide hydrolase activity of whole bacterial cells furnished the corresponding vicinal diols 1b-8b as intermediates; these (spontaneously) underwent ring closure to yield cyclic products 1c-6c through an enzyme-triggered cascade reaction. In particular, cis-configured substrates (1a, 3a, 5a, 7a) were transformed in an enantioconvergent fashion, which resulted in the formation of single stereoisomeric products in 100% des and up to 92% ees from the racemates.