CuCl-catalyzed aerobic oxidative thiocyanation of arylboronic acids at room temperature

July 29, 2024

• Title:       

  CuCl-catalyzed aerobic oxidative thiocyanation of arylboronic acids at room temperature

• Image Source:

  A mild copper-catalyzed aerobic oxidative thiocyanation of arylboronic acids with TMSNCS

• Mark:

  Table 2

• Associated context:

  As listed in Table 2, not only arylboronic acids bearing with electron-donating groups (1a-1f) could afford the desired products in good yields (Entries 1-6, Table 2), but those arylboronic acids with electron-withdrawing groups (1g-1m) also worked well under the standard procedure and their corresponding aryl thiocyanates were obtained in moderate to good yields (Entries 7-13, Table 2).