Experimental and Calculated ESR Data of Oxidized Mononuclear Ru-Vinyl Complexes

August 16, 2024

• Title:       

  Experimental and Calculated ESR Data of Oxidized  Mononuclear Ru-Vinyl Complexes

• Image Source:

  Ruthenium complexes with vinyl, styryl, and vinylpyrenyl ligands: A case of non-innocence in organometallic chemistry

• Mark:

  Table 4

• Associated context:

  Computed ESR  parameters as they are given in Table 4 fully reproduce the experimentally observed small g-anisotropies ∆g, the systematic decrease of ∆g with increasing π-conjugation and lower metal character of the SOMO as well as the small deviations of the average g-values from ge.