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Basic Information
| CAS No.: | 106-88-7 |
|---|---|
| Name: | 1,2-Epoxybutane |
| Article Data: | 106 |
| Molecular Structure: | |
|
|
|
| Formula: | C4H8O |
| Molecular Weight: | 72.1069 |
| Synonyms: | Butane,1,2-epoxy- (8CI);Oxirane, ethyl- (9CI);1,2-Butene oxide;1,2-Butyleneepoxide;1,2-Butylene oxide;1,2-Epoxybutane;1-Butene oxide;1-Butylene oxide;2-Ethyloxirane;Butene 1,2-epoxide;DL-1,2-Epoxybutane;Ethylethylene oxide;Ethyloxirane;NSC 24240;a-Butylene oxide; |
| EINECS: | 203-438-2 |
| Density: | 0.88 g/cm3 |
| Melting Point: | -130oC |
| Boiling Point: | 63.4 °C at 760 mmHg |
| Flash Point: | -15 °C |
| Solubility: | 86.8g/L at 25℃ |
| Appearance: | colourless liquid with an unpleasant smell |
| Hazard Symbols: |
 F,  Xn
|
| Risk Codes: | 11-20/21/22-36/37/38-40-52/53 |
| Safety: | 9-16-29-36/37-61-19 |
| Transport Information: | UN 3022 3/PG 2 |
| PSA: | 12.53000 |
| LogP: | 0.79520 |
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Synthetic route
- 106-98-9
1-butylene
- 80-15-9
Cumene hydroperoxide
A
- 106-88-7
ethyloxirane
B
- 617-94-7
1-methyl-1-phenylethyl alcohol
Conditions
| Conditions | Yield |
|---|---|
| With Ti-HMS at 95℃; under 26252.6 Torr; | A 98.6% B n/a |
...Expand
Conditions
| Conditions | Yield |
|---|---|
| With phosphotungstic acid; phosphoric acid tributyl ester; dihydrogen peroxide In toluene at 70℃; under 3750.38 Torr; for 5h; Temperature; Pressure; | 96.8% |
| With tert.-butylhydroperoxide; 2C13H10N3O2(1-)*MoO2(2+) In methanol; dichloromethane for 1h; Catalytic behavior; Reagent/catalyst; | 91% |
| With dihydrogen peroxide; teterabutylammonium In acetonitrile at 31.85℃; for 8h; | 88% |
Conditions
| Conditions | Yield |
|---|---|
| With Ph4SbOMe In dichloromethane at 40℃; for 3h; | 64% |
| With potassium hydroxide | |
| With Ph4SbOMe In dichloromethane at 40℃; for 4h; | 75 % Chromat. |
- 26106-95-6
2-chloro-1-butanol
- 106-88-7
ethyloxirane
Conditions
| Conditions | Yield |
|---|---|
| With Ph4SbOMe In dichloromethane at 40℃; for 3h; | 10% |
Conditions
| Conditions | Yield |
|---|---|
| With oxygen at 500℃; under 5148.6 Torr; |
Conditions
| Conditions | Yield |
|---|---|
| With potassium hydroxide |
Conditions
| Conditions | Yield |
|---|---|
| at 83.4 - 137℃; Kinetics; further compounds; |
- 930-22-3
epoxybutene
A
- 106-88-7
ethyloxirane
B
- 627-27-0
homoalylic alcohol
C
- 6117-91-5
(E/Z)-2-buten-1-ol
D
- 123-72-8
butyraldehyde
E
- 123-73-9
crotonaldehyde
F
- 71-36-3
butan-1-ol
Conditions
| Conditions | Yield |
|---|---|
| With hydrogen; at 30℃; under 760 Torr; for 8h; Product distribution; Mechanism; catalytic hydrogenation of the title compound in the presence of various catalysts (cationic rhodium complexes); influence of the type of catalyst's ligand, reaction time and pressure on the activity of catalysts; | A 2.1 % Chromat. B 16.5 % Chromat. C 11.7 % Chromat. D 4.4 % Chromat. E 44.3 % Chromat. F 1.7 % Chromat. |
| With hydrogen at 80℃; under 16274.9 Torr; Autoclave; |
...Expand
- 24068-63-1
2-bromo-1-butanol
- 106-88-7
ethyloxirane
Conditions
| Conditions | Yield |
|---|---|
| With potassium carbonate In 1,4-dioxane at 25℃; for 120h; Yield given; |
- 39972-78-6
allyl t-butyl peroxide
- 106-88-7
ethyloxirane
Conditions
| Conditions | Yield |
|---|---|
| With tert-butyl peroxyacetate at 110℃; under 0.001 Torr; for 12h; |
Raw Materials
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1,2-Epoxybutane
Toxicity Data With Reference
| 1. | skn-rbt 500 mg/24H MLD | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,770. | ||
| 2. | eye-rbt 100 mg/24H MOD | 85JCAE Prehled Prumyslove Toxikologie; Organicke Latky Marhold, J.,Prague, Czechoslovakia.: Avicenum,1986,770. | ||
| 3. | mmo-klp mmol/L | MUREAV Mutation Research. 89 (1981),269. | ||
| 4. | trn-dmg-orl 5 pph | ENMUDM Environmental Mutagenesis. 7 (1985),349. | ||
| 5. | mma-ssp 1600 μmol/L | TCMUD8 Teratogenesis, Carcinogenesis, and Mutagenesis. 3 (1983),75. | ||
| 6. | orl-rat LD50:500 mg/kg | NTIS** National Technical Information Service. (Springfield, VA 22161) (Formerly U.S. Clearinghouse for Scientific and Technical Information) PB81-168510 . | ||
| 7. | ihl-rat LCLo:4000 ppm/4H | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. | ||
| 8. | skn-rbt LD50:2100 mg/kg | AIHAAP American Industrial Hygiene Association Journal. 23 (1962),95. |
Consensus Reports
NTP Carcinogenesis Studies (inhalation); Clear Evidence: rat; No Evidence: mouse NTPTR* National Toxicology Program Technical Report Series. (Research Triangle Park, NC 27709) No. NTP-TR-329 (1988). . Community Right-To-Know List. EPA Genetic Toxicology Program. Reported in EPA TSCA Inventory.
Safety Profile
Confirmed carcinogen with experimental carcinogenic data. Moderately toxic by ingestion and skin contact. Mildly toxic by inhalation. Experimental reproductive effects. Mutation data reported. Dangerous fire hazard when exposed to heat, flame, or powerful oxidizers. To fight fire, use dry chemical, water spray, mist or fog, alcohol foam. When heated to decomposition it emits acrid smoke and fumes.
Standards and Recommendations
DFG MAK: Animal Carcinogen, Suspected Human Carcinogen