Welcome to LookChem.com Sign In|Join Free

CAS

  • or

12029-98-0

Post Buying Request

12029-98-0 Suppliers

Recommended suppliersmore

  • Product
  • FOB Price
  • Min.Order
  • Supply Ability
  • Supplier
  • Contact Supplier

12029-98-0 Usage

Physical Properties

White crystals; hygroscopic; density 4.98 g/cm3; decomposes around 300°C; highly soluble in water; soluble in nitric acid; insoluble in ethanol, ether and carbon disulfide.

Uses

Different sources of media describe the Uses of 12029-98-0 differently. You can refer to the following data:
1. Iodine pentoxide is used for analysis of carbon monoxide and for CO removal from air. It also is used as an oxidizing agent in other oxidation reactions.
2. Iodine (V) oxide is used as an oxidizing agent to remove carbon monoxide from gas.
3. Oxidizes carbon monoxide to carbon dioxide with the formn of iodine (Ditte's reaction, which proceeds rapidly at 65° or above, but slowly at room temp). This reaction is used in gas analysis and for removing carbon monoxide from the air (in respirators preferably in presence of some H2SO4).

Preparation

Iodine pentoxide is prepared by dehydration of iodic acid at 240°C. 2HIO3 → I2O5 + H2O

Reactions

Iodine pentoxide is a strong oxidizing agent and reacts with various oxidizable substances. It oxidizes carbon monoxide to carbon dioxide. The reaction is quantitative and used to measure carbon monoxide in the air: I2O5 + 5CO → I2 + 5CO2 It reacts with hydrogen sulfide, forming sulfur dioxide: 3I2O5 + 5H2S → 3I2 + 5SO2 + 5H2O Oxidation reaction also occurs with hydrogen chloride, metal hydrides and a number of metal salts. It dissolves in water reacting to form iodic acid: I2O5 + H2O → 2HIO3 Dissociation into iodine and oxygen commences when heated above 270°C.

Chemical Properties

needle shaped crystals

Physical properties

White crystals; hygroscopic; density 4.98 g/cm3; decomposes around 300°C;highly soluble in water; soluble in nitric acid; insoluble in ethanol, ether andcarbon disulfide.

Check Digit Verification of cas no

The CAS Registry Mumber 12029-98-0 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,2,0,2 and 9 respectively; the second part has 2 digits, 9 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 12029-98:
(7*1)+(6*2)+(5*0)+(4*2)+(3*9)+(2*9)+(1*8)=80
80 % 10 = 0
So 12029-98-0 is a valid CAS Registry Number.
InChI:InChI=1/I2O5/c3-1(4)7-2(5)6

12029-98-0 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
  • Price
  • Detail
  • Alfa Aesar

  • (87682)  Iodine(V) oxide, 98%   

  • 12029-98-0

  • 25g

  • 881.0CNY

  • Detail
  • Alfa Aesar

  • (87682)  Iodine(V) oxide, 98%   

  • 12029-98-0

  • 100g

  • 2562.0CNY

  • Detail
  • Aldrich

  • (229709)  Iodopentoxide  99.99% trace metals basis

  • 12029-98-0

  • 229709-25G

  • 1,210.95CNY

  • Detail
  • Aldrich

  • (229709)  Iodopentoxide  99.99% trace metals basis

  • 12029-98-0

  • 229709-250G

  • 8,248.50CNY

  • Detail
  • Aldrich

  • (278890)  Iodopentoxide  ≥98%

  • 12029-98-0

  • 278890-25G

  • 939.51CNY

  • Detail
  • Aldrich

  • (278890)  Iodopentoxide  ≥98%

  • 12029-98-0

  • 278890-100G

  • 3,045.51CNY

  • Detail

12029-98-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 12, 2017

Revision Date: Aug 12, 2017

1.Identification

1.1 GHS Product identifier

Product name diiodine pentaoxide

1.2 Other means of identification

Product number -
Other names Diiodine pentoxide,Iodic anhydride

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:12029-98-0 SDS

12029-98-0Synthetic route

iodine
7553-56-2

iodine

dinitrogen pentoxide
10102-03-1

dinitrogen pentoxide

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) N2O5 (from P2O5 with HNO3); heating first to 50°C, at the end of reaction to 90°C;; drying on heating, removal of excessive iodine by sublimation; recrystallization in water several times, drying on heating to 220°C;;40%
In neat (no solvent) N2O5 (from P2O5 with HNO3); heating first to 50°C, at the end of reaction to 90°C;; drying on heating, removal of excessive iodine by sublimation; recrystallization in water several times, drying on heating to 220°C;;40%
In tetrachloromethane byproducts: O2; reaction of N2O5 with soln. of I2 in CCl4 at 0°C; at higher temp. formation of some O2;;
In tetrachloromethane byproducts: O2; reaction of N2O5 with soln. of I2 in CCl4 at 0°C; at higher temp. formation of some O2;;
potassium iodide
7681-11-0

potassium iodide

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In water passing stream of O3 quickly through neutral soln.;;
In water passing stream of O3 quickly through neutral soln.;;0%
In neat (no solvent)
In neat (no solvent)
In water
perchloric anhydride
12015-53-1

perchloric anhydride

iodine
7553-56-2

iodine

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In not given byproducts: HClO4; I2 reacts with chlorine heptoxide at normal temp. under explosion, at low temp. slowlier; reactn. product: white powder: heating (100°C) -> setting free HClO4, residue: I2O5;;
iodine
7553-56-2

iodine

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) reaction by influence of O3 on solid, dry I2;;
oxygen
80937-33-3

oxygen

potassium iodide
7681-11-0

potassium iodide

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

periodate
15056-35-6

periodate

C

iodate
15454-31-6

iodate

Conditions
ConditionsYield
With Na2CO3 or K2CO3 In not given reaction by use of a O3-O2 mixture in a Na2CO3- or K2CO3-containing alcaline 0.1n-KI soln. for a period of 20-30 min.;;
oxygen
80937-33-3

oxygen

potassium iodide
7681-11-0

potassium iodide

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In not given reaction by absorption of O3-containing O2 in a 3-8% KI soln.;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

iodine
7553-56-2

iodine

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

iodine trichloride
865-44-1

iodine trichloride

Conditions
ConditionsYield
In neat (no solvent) from ClO2 (from KClO3 and H2SO4) and dry iodine;; ICl3 evaporated on water bath by grinding; I2O5 very pure;;
In neat (no solvent) from ClO2 (from KClO3 and H2SO4) and dry iodine;; ICl3 evaporated on water bath by grinding; I2O5 very pure;;
chlorine dioxide
10049-04-4, 25052-55-5

chlorine dioxide

iodine
7553-56-2

iodine

chlorine
7782-50-5

chlorine

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) on heating I2 with euchlorine;;
In neat (no solvent) on heating I2 with euchlorine;;
In neat (no solvent)
iodine
7553-56-2

iodine

dinitrogen pentoxide
10102-03-1

dinitrogen pentoxide

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

iodine(III) nitrate

iodine(III) nitrate

Conditions
ConditionsYield
In neat (no solvent) from solid N2O5 and dry I2;; product mixture;;
iodine
7553-56-2

iodine

oxygen
80937-33-3

oxygen

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) at red heat with platinum asbestos or -sponge;;0%
Electric Arc; mixture of I2O5 and other iodine oxides;;
In neat (no solvent) 90-100atm O2-pressure; heating to 250°C;;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

iodine trichloride
865-44-1

iodine trichloride

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) main product I2O5;;
In neat (no solvent) main product I2O5;;
hypochlorous anhydride
7791-21-1

hypochlorous anhydride

iodine trichloride
865-44-1

iodine trichloride

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
In neat (no solvent) passing Cl2O over ICl3, surface reaction;;
In neat (no solvent) passing Cl2O over ICl3, surface reaction;;
acetic acid
64-19-7

acetic acid

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

hydrogen fluoride dimer

hydrogen fluoride dimer

Conditions
ConditionsYield
In acetic acid heating with glacial acetic acid;;
iodine heptafluoride
16921-96-3, 596797-38-5

iodine heptafluoride

acetone
67-64-1

acetone

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

iodine
7553-56-2

iodine

Conditions
ConditionsYield
In acetone heating;; pptn.;;
HIO3*I2O5=HI3O8
147795-17-3

HIO3*I2O5=HI3O8

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In solid heated to 210°C in a dynamic vacuum for 12 h;
Be(2+)*4IO3(1-)*2H(1+)*6H2O=Be(IO3)2*2HIO3*6H2O

Be(2+)*4IO3(1-)*2H(1+)*6H2O=Be(IO3)2*2HIO3*6H2O

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

beryllium periodate

beryllium periodate

Conditions
ConditionsYield
In neat (no solvent) heating (1173 K); differential thermal analysis, thermogravimetry, differential scanning calorimetry;
2,3,5,6-tetraiodo-[1,4]benzoquinone
576-59-0

2,3,5,6-tetraiodo-[1,4]benzoquinone

nitric acid
7697-37-2

nitric acid

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) heating to 200-250°C;;
In neat (no solvent) heating to 200-250°C;;
iodine(III) nitrate

iodine(III) nitrate

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: nitrous gases, N2O5; on heating to 130°C;; pure I2O5;;
dinitrogen pentoxide
10102-03-1

dinitrogen pentoxide

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
With iodine
iodic acid
7782-68-5

iodic acid

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) heating to 250°C in vacuum for 100h; adsorption of H2O discussed;; pure I2O5;;
In neat (no solvent) above 110°C;;
In neat (no solvent) byproducts: H2O; dehydration;;
periodic acid
13444-71-8

periodic acid

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

water
7732-18-5

water

C

oxygen
80937-33-3

oxygen

D

ozone
10028-15-6

ozone

Conditions
ConditionsYield
In neat (no solvent) decompn. by heating at 135-145 °C;;
In neat (no solvent) decompn. by heating at 135-145 °C;;
periodic acid
13444-71-8

periodic acid

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
With acetyl chloride In acetic anhydride pptn.;;
In neat (no solvent) gradually decompn. at 138°C;;
In neat (no solvent) gradually decompn. at 138°C;;
With acetyl chloride In acetic anhydride pptn.;;
iodine heptafluoride
16921-96-3, 596797-38-5

iodine heptafluoride

ethyl acetate
141-78-6

ethyl acetate

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

hydrogen fluoride dimer

hydrogen fluoride dimer

Conditions
ConditionsYield
In ethyl acetate heating with ethyl acetate;;
carbon tetraiodide
507-25-5

carbon tetraiodide

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
With oxygen In neat (no solvent) Irradiation (UV/VIS); oxidation in the light of a mercury-lamp, formation of I2O5;;
periodic acid
10450-60-9

periodic acid

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

water
7732-18-5

water

C

oxygen
80937-33-3

oxygen

D

ozone
10028-15-6

ozone

Conditions
ConditionsYield
In neat (no solvent) decompn. by heating at 135-145 °C;;
In neat (no solvent) decompn. by heating at 135-145 °C;;
periodic acid
10450-60-9

periodic acid

iodine pentoxide
12029-98-0

iodine pentoxide

Conditions
ConditionsYield
In neat (no solvent) byproducts: H2O, O2; heating at ambient pressure; begin at 138°C;;
In neat (no solvent) byproducts: H2O, O2; heating at ambient pressure; begin at 138°C;;
beryllium periodate

beryllium periodate

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

beryllium oxide

beryllium oxide

Conditions
ConditionsYield
In neat (no solvent) Kinetics; decompn. at 623 K;
nitryl perchlorate

nitryl perchlorate

iodine
7553-56-2

iodine

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

Iodine monochloride
7790-99-0

Iodine monochloride

Conditions
ConditionsYield
In neat (no solvent) heating;;
In neat (no solvent) heating;;
iodine(III) oxide

iodine(III) oxide

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

iodine
7553-56-2

iodine

Conditions
ConditionsYield
In neat (no solvent) byproducts: O2; heating to 125-130°C;;
iodine(III) perchlorate * 2H2O

iodine(III) perchlorate * 2H2O

A

iodine pentoxide
12029-98-0

iodine pentoxide

B

chlorine
7782-50-5

chlorine

Conditions
ConditionsYield
In neat (no solvent) on storage in desiccator;;
iodine pentoxide
12029-98-0

iodine pentoxide

iodine pentafluoride

iodine pentafluoride

iodine(V) oxofluoride
19058-78-7

iodine(V) oxofluoride

Conditions
ConditionsYield
In neat (no solvent, solid phase) I2O5 was loaded into a Kel-F reactor; then IF5 was added; the mixt. was heated to 105°C and held at this temp. for 50 min; removing all volatiles in vac. at 25°C;99%
iodine pentoxide
12029-98-0

iodine pentoxide

(237)neptunium(IV) oxide

(237)neptunium(IV) oxide

water
7732-18-5

water

(237)neptunium(V) iodate

(237)neptunium(V) iodate

Conditions
ConditionsYield
With AgNO3 In water High Pressure; NpO2 (0.041 mmol), AgNO3 (0.039 mmol), and I2O5 (0.039 mmol) were loadedin an autoclave; H2O was added; the autoclave was sealed and placed in a preheated furnace for 3 d at 180°C; the box furnace was cooled at 9°/h to 23°C; EDX anal.;99%
iodine pentoxide
12029-98-0

iodine pentoxide

water
7732-18-5

water

vanadia

vanadia

potassium carbonate
584-08-7

potassium carbonate

KVO2(IO3)2(H2O), α

KVO2(IO3)2(H2O), α

Conditions
ConditionsYield
In water High Pressure; mixt. of K2CO3 (0.75 mmol), V2O5 (0.5 mmol), I2O5 (2 mmol) and H2O heated at 155°C in autoclave for 4 d, cooled to room temp. at 3°/h; washed with water and EtOH, dried in air; powder X-ray diffraction;95%
iodine pentoxide
12029-98-0

iodine pentoxide

water
7732-18-5

water

vanadia

vanadia

bismuth(III) oxide
1304-76-3

bismuth(III) oxide

potassium carbonate
584-08-7

potassium carbonate

A

bismuth iodate

bismuth iodate

KVO2(IO3)2(H2O), β

KVO2(IO3)2(H2O), β

Conditions
ConditionsYield
In water mixt. of K2CO3, V2O5, I2O5, Bi2O3 and H2O heated at 230°C in autoclave for 4 d, cooled to room temp. at 3°/h; washed with water and EtOH, dried in air; powder X-ray diffraction;A n/a
B 92%
iodine pentoxide
12029-98-0

iodine pentoxide

silver nitrate

silver nitrate

AgI3O8

AgI3O8

Conditions
ConditionsYield
In water at 210℃; for 72h; Autoclave;92%
bismuth(III) chloride

bismuth(III) chloride

iodine pentoxide
12029-98-0

iodine pentoxide

potassium fluoride dihydrate

potassium fluoride dihydrate

3IO3(1-)*K(1+)*Bi(3+)*HO(1-)

3IO3(1-)*K(1+)*Bi(3+)*HO(1-)

Conditions
ConditionsYield
Stage #1: bismuth(III) chloride; iodine pentoxide; potassium fluoride dihydrate In water for 2h;
Stage #2: In water at 210℃; for 96h; Autoclave;
90.2%
iodine pentoxide
12029-98-0

iodine pentoxide

uranyl nirate hexahydrate

uranyl nirate hexahydrate

sodium hydrogencarbonate
144-55-8

sodium hydrogencarbonate

2Na(1+)*[UO2(OIO2)4(OH2)](2-)=Na2[UO2(OIO2)4(OH2)]

2Na(1+)*[UO2(OIO2)4(OH2)](2-)=Na2[UO2(OIO2)4(OH2)]

Conditions
ConditionsYield
With (C5H4N)2; HCl In water High Pressure; sealed, heated to 120°C for 7 d; cooled at an averaged rate of 9°C/h to room temp., washed (H2O, MeOH), dried;90%
iodine pentoxide
12029-98-0

iodine pentoxide

palladium(II) nitrate dihydrate

palladium(II) nitrate dihydrate

Pd(2+)*2IO3(1-)=Pd(IO3)2

Pd(2+)*2IO3(1-)=Pd(IO3)2

Conditions
ConditionsYield
With Li2CO3 In water High Pressure; heating mixt. of palladium compd., I2O5, Li2CO3 and water at 200°C for 4 d; slow cooling to room temp. at rate of 6°C/h, isolation of crystals, XRD;90%
In water High Pressure; heating mixt. of palladium compd., I2O5 and water at 200°C for 4 d;0%
iodine pentoxide
12029-98-0

iodine pentoxide

lithium carbonate
554-13-2

lithium carbonate

potassium carbonate
584-08-7

potassium carbonate

3IO3(1-)*2Li(1+)*K(1+)

3IO3(1-)*2Li(1+)*K(1+)

Conditions
ConditionsYield
In water at 230℃; for 72h; Temperature; Solvent; Time; Autoclave;90%
iodine pentoxide
12029-98-0

iodine pentoxide

barium(II) chloride dihydrate
10361-37-2

barium(II) chloride dihydrate

lithium chloride

lithium chloride

5IO3(1-)*7Ba(2+)*9Cl(1-)

5IO3(1-)*7Ba(2+)*9Cl(1-)

Conditions
ConditionsYield
In water at 210℃; for 96h;90%
iodine pentoxide
12029-98-0

iodine pentoxide

lanthanide(III)chloride heptahydrate

lanthanide(III)chloride heptahydrate

lithium chloride

lithium chloride

5IO3(1-)*2La(3+)*Cl(1-)

5IO3(1-)*2La(3+)*Cl(1-)

Conditions
ConditionsYield
In water at 210℃; for 96h;90%
iodine pentoxide
12029-98-0

iodine pentoxide

cerium(III) nitrate hexahydrate

cerium(III) nitrate hexahydrate

lead(II) chloride

lead(II) chloride

Ce3Pb3(iodate)13(μ3-O)

Ce3Pb3(iodate)13(μ3-O)

Conditions
ConditionsYield
In water High Pressure; mixt. of Ce nitrate, PbCl2, I2O5, and H2O heated at 200°C in stainless steel vessel for 5 d; slow cooling to 30°C at 6°C/h, crystals isolated, washed with water, dried in air; XRD, EDS;89%
iodine pentoxide
12029-98-0

iodine pentoxide

palladium diacetate
3375-31-3

palladium diacetate

silver(l) oxide
20667-12-3

silver(l) oxide

Ag(1+)*Pd(2+)*3IO3(1-)=AgPd(IO3)3

Ag(1+)*Pd(2+)*3IO3(1-)=AgPd(IO3)3

Conditions
ConditionsYield
In water High Pressure; heating mixt. of palladium compd., I2O5, silver oxide and water at 200°C for 4 d; slow cooling to room temp. at rate of 6°C/h, isolation of crystals, washing with hot water, drying in air, XRD;85%
iodine pentoxide
12029-98-0

iodine pentoxide

hydrogen fluoride
7664-39-3

hydrogen fluoride

vanadia

vanadia

caesium carbonate
534-17-8

caesium carbonate

CsVO2F(IO3)

CsVO2F(IO3)

Conditions
ConditionsYield
In water at 160℃; for 72h; Autoclave;85%
iodine pentoxide
12029-98-0

iodine pentoxide

lanthanide(III)chloride heptahydrate

lanthanide(III)chloride heptahydrate

2IO3(1-)*La(3+)*Cl(1-)

2IO3(1-)*La(3+)*Cl(1-)

Conditions
ConditionsYield
In water at 210℃; for 96h;85%
iodine pentoxide
12029-98-0

iodine pentoxide

cerium(III) nitrate hexahydrate

cerium(III) nitrate hexahydrate

cerium triiodate

cerium triiodate

Conditions
ConditionsYield
In water High Pressure; sealed in a Teflon-lined autoclave, heated in an oven at 443 K for one wk under autogenously generated pressure, cooled slowly to room temp.; the crystals washed with deionized water and anhyd. acetone;84%
In water at 180℃; for 24h; Autoclave;
iodine pentoxide
12029-98-0

iodine pentoxide

lanthanum(III) nitrate hexahydrate

lanthanum(III) nitrate hexahydrate

vanadia

vanadia

La(3+)*V2O6(2-)*IO3(1-)=LaV2O6(IO3)

La(3+)*V2O6(2-)*IO3(1-)=LaV2O6(IO3)

Conditions
ConditionsYield
In water High Pressure; a mixt. of La salt, V2O5, I2O5 and H2O sealed in an autoclave, heated at250°C for 4 d; cooled to room temp. at a rate of 6°C/h, washed (hot H2O, EtOH), dried in air; EDS elem. anal.;84%
niobium(V) oxide

niobium(V) oxide

iodine pentoxide
12029-98-0

iodine pentoxide

barium iodate monohydrate

barium iodate monohydrate

Ba(2+)*NbO(IO3)5(2-)=BaNbO(IO3)5

Ba(2+)*NbO(IO3)5(2-)=BaNbO(IO3)5

Conditions
ConditionsYield
In water High Pressure; the mixt. of Ba(IO3)2*H2O, Nb2O5, I2O5 in water was sealed in an autoclave equipped with a Teflon liner at 230°C for 4 days; powder X-ray diffraction;83%
iodine pentoxide
12029-98-0

iodine pentoxide

silver nitrate

silver nitrate

AgI3O8

AgI3O8

Conditions
ConditionsYield
In water at 210℃; for 72h; Autoclave;83%
indium(III) oxide

indium(III) oxide

iodine pentoxide
12029-98-0

iodine pentoxide

phosphoric acid
86119-84-8, 7664-38-2

phosphoric acid

water
7732-18-5

water

HO4P(2-)*H2O*IO3(1-)*In(3+)

HO4P(2-)*H2O*IO3(1-)*In(3+)

Conditions
ConditionsYield
at 230℃; for 72h; pH=0.5 - 2; Autoclave;83%
iodine pentoxide
12029-98-0

iodine pentoxide

indium(III) nitrate monohydrate

indium(III) nitrate monohydrate

silver nitrate

silver nitrate

4IO3(1-)*Ag(1+)*In(3+)

4IO3(1-)*Ag(1+)*In(3+)

Conditions
ConditionsYield
With nitric acid In water at 230℃; for 72h; Autoclave;83%
iodine pentoxide
12029-98-0

iodine pentoxide

thallium chloride

thallium chloride

uranium(VI) trioxide

uranium(VI) trioxide

2Tl(1+)*3UO2(2+)*4IO3(1-)*2O(2-)=Tl2[(UO2)3(IO3)4O2]

2Tl(1+)*3UO2(2+)*4IO3(1-)*2O(2-)=Tl2[(UO2)3(IO3)4O2]

Conditions
ConditionsYield
In water High Pressure; at 200°C for 72 h; autoclave cooled at 9°C/h to 23°C; mother liquors decanted; washed (MeOH); dried;82%
lanthanum(III) oxide

lanthanum(III) oxide

iodine pentoxide
12029-98-0

iodine pentoxide

vanadia

vanadia

A

VO2(1+)*IO3(1-)*2H2O=VO2(IO3)*2H2O

VO2(1+)*IO3(1-)*2H2O=VO2(IO3)*2H2O

B

La(3+)*[VO(OIO2)5](3-)=La[VO(OIO2)5]

La(3+)*[VO(OIO2)5](3-)=La[VO(OIO2)5]

Conditions
ConditionsYield
In water High Pressure; a mixt. of La2O3, V2O5, I2O5 and H2O sealed in an autoclave, heated at 250°C for 10 d; cooled to room temp. at a rate of 6°C/h, washed (H2O, EtOH), dried in air, sepd. manually; EDS elem. anal.;A 5%
B 82%
iodine pentoxide
12029-98-0

iodine pentoxide

water
7732-18-5

water

vanadia

vanadia

potassium carbonate
584-08-7

potassium carbonate

K(1+)*(VO)2O2(IO3)3(1-)=K(VO)2O2(IO3)3

K(1+)*(VO)2O2(IO3)3(1-)=K(VO)2O2(IO3)3

Conditions
ConditionsYield
In water mixt. of K2CO3 (0.4 mmol), V2O5 (0.5 mmol), I2O5 (2 mmol) and H2O heatedat 160°C in autoclave for 4 d, cooled to room temp. at 3° /h; washed with water and EtOH, dried in air; powder X-ray diffraction;82%
iodine pentoxide
12029-98-0

iodine pentoxide

vanadia

vanadia

zinc(II) acetate dihydrate
5970-45-6

zinc(II) acetate dihydrate

IO3(1-)*Zn2VO4(1+)

IO3(1-)*Zn2VO4(1+)

Conditions
ConditionsYield
In water at 190℃; for 72h; Autoclave; High pressure;81%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

iodine pentoxide
12029-98-0

iodine pentoxide

In(3+)*3NO3(1-)*20.5H2O=In(NO3)3*20.5H2O

In(3+)*3NO3(1-)*20.5H2O=In(NO3)3*20.5H2O

water
7732-18-5

water

2In(3+)*6IO3(1-)*(NC5H4)2*2H2O=[In2(IO3)6(H2O)((NC5H4)2)]*H2O

2In(3+)*6IO3(1-)*(NC5H4)2*2H2O=[In2(IO3)6(H2O)((NC5H4)2)]*H2O

Conditions
ConditionsYield
In water High Pressure; equimol., In salt and bipy added to a soln. of I2O5 with stirring, stirred for 30 min, heated at 100°C for 7 d; elem. anal., TGA;80%
[2,2]bipyridinyl
366-18-7

[2,2]bipyridinyl

iodine pentoxide
12029-98-0

iodine pentoxide

vanadia

vanadia

(2,2'-bipyridine)(VO2)(iodate)
1178904-76-1

(2,2'-bipyridine)(VO2)(iodate)

Conditions
ConditionsYield
In water High Pressure; addn. of vanadium compd. and bipyridine deriv. to stirred aq. soln. of iodine(V) oxide, stirring for 30 min, heating at 120°C for 6 d; isolation of crystals, elem. anal.;80%

12029-98-0Relevant articles and documents

Maneva, M.,Georgiev, M.

, p. 867 - 872 (1989)

Fluorine-oxygen exchange reactions in IF5, IF7, and IF5O

Christe, Karl O.,Wilson, William W.,Wilson, Richard D.

, p. 904 - 908 (2008/10/08)

When reacted with alkali-metal nitrates, IF5 readily exchanges two fluorine ligands for a doubly bonded oxygen atom. In all cases MIF4O salts (M = Li, K, Cs) and FNO2 are formed as the primary products. The FNO2 byproduct undergoes a fast secondary reaction with MNO3 to yield equimolar amounts of N2O5 and MF. The N2O5 decomposes to N2O4 and 0.5 mol of O2, while the MF, depending on the nature of M, does or does not undergo complexation with the excess of IF5. Pure MIF4O salts, free of MF or MF·nIF5 byproducts, were prepared from MF, I2O5, and IF5 in either CH3CN or IF5 as a solvent. The new compounds LiIF4O, NaIF4O, RbIF4O, and NOIF4O were characterized by vibrational spectroscopy. It was also shown that, contrary to a previous report, FNO2 does not form a stable adduct with IF5 at temperatures as low as -78°C. An excess of IF7 reacts with MNO3 (M = Li, Na) to give MF, FNO2, IF5, and 0.5 mol of O2, but surprisingly no IF5O. With CsNO3, the reaction products are analogous, except for the CsF reacting with both the IF5 product and the excess of IF7 to give CsIF6·2IF5 and CsIF8, respectively. When in the IF7 reaction an excess of LiNO3, is used, the IF5 product undergoes further reaction with LiNO3, as described above. The IF5O molecule was found to be rather unreactive. It does not react with either LiF or CsF at 25 or 60°C or with LiNO3 or CsNO3 at 25°C. At 60°C with LiNO3, it slowly loses oxygen, with the IF5 product reacting to yield LiIF4O, as described above.

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 12029-98-0