611-13-2Relevant articles and documents
Oxidative esterification of renewable furfural on cobalt dispersed on ordered porous nitrogen-doped carbon
Yin, Defeng,Zheng, Yanxia,Yang, Lixi,Li, Shuyue,Zhu, Daqing,Guo, Yafei,Zuo, Cuncun,Li, Yuchao,Huang, Haofei,Wang, Ming
, p. 3280 - 3287 (2021)
A series of highly dispersed cobalt-based catalysts on N-doped ordered porous carbon (Co-NOPC) were synthesized using the sacrificiallate method. MCM-41, ZSM-5 and SBA-15 were employed as hard templates with 2,2′-bipyridine as the ligand. The physical and
High-efficiency oxidative esterification of furfural to methylfuroate with a non-precious metal Co-N-C/MgO catalyst
Huo, Na,Ma, Hong,Wang, Xinhong,Wang, Tianlong,Wang, Gang,Wang, Ting,Hou, Leilei,Gao, Jin,Xu, Jie
, p. 1148 - 1154 (2017)
From both fundamental and practical perspectives, the production of chemicals from biomass resources using high-efficiency non-precious metal catalysts is important. However, many processes require addition of stoichiometric or excess quantities of base,
On the nature of the active sites in the selective oxidative esterification of furfural on Au/ZrO2 catalysts
Ampelli,Barbera,Centi,Genovese,Papanikolaou,Perathoner,Schouten,van der Waal
, p. 127 - 134 (2016)
Two catalysts, based on gold on zirconia and prepared in the same way, except for the different thermal treatment in air after the addition of gold (0.4% wt), show a quite different behavior in furfural oxidative esterification, particularly in the select
Study of the oxidative esterification of furfural catalyzed by Au25(glutathione)18 nanocluster deposited on zirconia
Shahin, Zahraa,Rataboul, Franck,Demessence, Aude
, (2021)
Au/ZrO2 catalyst prepared from Au25(SG)18 nanoclusters (SG stands for glutathione) deposited on ZrO2 has shown to be an efficient system for the oxidative esterification of furfural with methanol. The influence of the supported nanoclusters was studied and showed that partial calcination of the supported nanoclusters at 300 °C was sufficient for a quantitative formation of methyl-2-furoate even in the absence of a base. In the presence of 0.27 mol% of Au, initial activities up to 250 h?1 were obtained at 100 °C under 6 bar of O2. The reactivity was extended to the oxidative esterification of furfuryl alcohol and the formation of various products and intermediates was discussed.
Ultrahigh-Content Nitrogen-doped Carbon Encapsulating Cobalt NPs as Catalyst for Oxidative Esterification of Furfural
Wang, Ting,Ma, Hong,Liu, Xin,Luo, Yang,Zhang, Shujing,Sun, Yuxia,Wang, Xinhong,Gao, Jin,Xu, Jie
, p. 1515 - 1522 (2019)
It is an attractive and challenging topic to endow non-noble metal catalysts with high efficiency via a nitrogen-doping approach. In this study, a nitrogen-doped carbon catalyst with high nitrogen content encapsulating cobalt NPs (CoOx@N-C(g))
A tunable process: Catalytic transformation of renewable furfural with aliphatic alcohols in the presence of molecular oxygen
Tong, Xinli,Liu, Zonghui,Yu, Linhao,Li, Yongdan
, p. 3674 - 3677 (2015)
The tunable transformation of renewable furfural with aliphatic alcohols in the presence of O2 is developed. Based on a nano Au catalyst and potassium carbonate, a 91.8% yield of methyl 2-furoate with 98.7% selectivity is obtained via the oxidative esterification in a furfural-methanol-O2 system; while a 91.4% yield of 3-(furan-2-yl-)-2-methylacrylaldehyde with 97.2% selectivity is attained via the oxidative condensation in a furfural-n-propanol-O2 system. This journal is
Metal silicotungstate salts as catalysts in furfural oxidation reactions with hydrogen peroxide
Rodrigues, Alana A.,da Silva, Márcio J.
, (2020)
In this work, metal cations exchanged silicotungstic acid salts were synthesized and evaluated as catalysts in furfural oxidative esterification reactions with hydrogen peroxide in alkyl alcohols solution. The protons of silicotungstic acid were totally e
Oxidation of furfural with H2O2 in the presence of a photogenerated iron catalyst
Moulines, Francoise,Ruiz, Jaime,Astruc, Didier
, p. C13 - C14 (1988)
Visible irradiation of a methanolic solution of furfural containing dilute aqueous H2O2 and PF6 (1: R=H, Cl or CH3) as catalyst yields methyl 2-furoate quantitatively.After photodecomplexation, the inorganic FeII,III catalyst can b
Oxidative esterification of furfural over Au-Pd/HAP-T and Au-Ag/HAP-T bimetallic catalysts supported on mesoporous hydroxyapatite nanorods
Radhakrishnan, Ramakrishnan,Kannan, Kathiravan,Kumaravel, Sakthivel,Thiripuranthagan, Sivakumar
, p. 45907 - 45922 (2016)
The conversion of furfural, a lignocellulose biomass, into fuels and value-added fine chemicals has attracted many researchers. In this study, structurally uniform and porous hydroxyapatite nanorods (HAP-T) with the gel composition 1Ca2+:0.66PO
Ultrafine Copper Oxide Particles Dispersed on Nitrogen-Doped Hollow Carbon Nanospheres for Oxidative Esterification of Biomass-Derived 5-Hydroxymethylfurfural
Gupta, Shyam Sunder R.,Vinu, Ajayan,Kantam, Mannepalli Lakshmi
, p. 259 - 269 (2021/03/01)
One-pot synthesis of furan-2,5-dimethylcarboxylate (FDMC) from 5-hydroxymethylfurfural (HMF) is highly demanding for the commercial production of polyethylene furanoate (PEF). Herein, a direct synthesis of FDMC is reported from oxidative esterification of HMF using ultrafine CuO particles dispersed on nitrogen-doped hollow carbon nanospheres (CuO/N?C?HNSs) as a catalyst and tert-butyl hydroperoxide (TBHP) as an oxidizing and methylating reagent. The CuO/N?C?HNSs was prepared through a template protection-sacrifice strategy using SiO2 as a sacrificial template and histidine as the precursor for N and C. N-doping facilitated a strong interaction between the support and copper species, affording formation of CuO nanoparticles of less than 10 nm in size. By virtue of the highly dispersed CuO nanoparticles and a high BET surface area 373 m2/g, the CuO/N?C?HNSsshows excellent catalytic performance in the selective conversion of HMF into FDMC affording 93 % yield of the desired product with a TON value of 49. Furthermore, the oxidative esterification involving SP3C?H bond functionalization is also demonstrated using the same catalyst.
