629-82-3Relevant articles and documents
Herriott,Picker
, p. 4521,4522, 4523 (1972)
Synthesis and characterization of a well-defined carbon nanohorn- supported molybdenum dioxo catalyst by SMART-EM imaging. surface structure at the atomic level
Kratish, Yosi,Nakamuro, Takayuki,Liu, Yiqi,Li, Jiaqi,Tomotsuka, Issei,Harano, Koji,Nakamura, Eiichi,Marks, Tobin J.
supporting information, p. 427 - 432 (2021/03/15)
The molybdenum dioxo catalyst CNH/MoO2 is prepared via direct grafting of (dme)MoO2Cl2 (dme = 1,2-dimethoxyethane) onto the graphitic surfaces of carbon nanohorn (CNH) substrates. The structure of this heterogeneous catalyst was characterized by SMART-EM, XPS, and ICP, and is found to have single isolated MoO2 species on the surface as well as a few multi-Mo species. The CNH/MoO2 complex exhibits excellent catalytic activity for polyethylene terephthalate (PET) hydrogenolysis, N-oxide reductions, and reductive carbonyl coupling, representing an informative model catalyst for structural and mechanistic investigations.
ALCOHOL DEHYDRATION CATALYST, PREPARATION METHOD THE SAME AND METHOD FOR PREPARING ALPHA-OLEFINS USING THE SAME
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Paragraph 0111-0123, (2020/11/24)
The present invention relates to a catalyst for dehydration of a primary alcohol, a method of preparing the same, and a method of producing an alpha-olefin using the same. The catalyst for dehydration of a primary alcohol according to the present invention has an excellent catalyst stability while having an excellent activity with respect to dehydration, and a high turnover frequency, such that a linear alpha-olefin with high purity may be produced with a high selectivity even in a case where a relatively small amount of a cocatalyst is added as compared with a homogeneous catalyst system.