Conformational Properties of 2,4-Methanoproline (2-Carboxy-2,4-methanopyrrolidine) in Peptides: Determination of Preferred Peptide Bond Conformation in Aqueous Solution by Proton Overhauser Measurements

DOI: 10.1021/ja00281a051

Source and publish data:

Journal of the American Chemical Society p. 6765 - 6773 (1986)

Update date:2022-08-03

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Authors:

Montelione, Gaetano T.

Hughes, Philip

Clardy, Jon

Scheraga, Harold A.

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Article abstract of DOI:10.1021/ja00281a051

The effects of replacing L-proline with a novel naturally occuring α-amino acid, 2,4-methanoproline (2-carboxy-2,4-methanopyrrolidine; 2,4-MePro), on the tertiary peptide bond cis/trans equilibrium have been investigated in small peptides by nuclear magne

Full text of DOI:10.1021/ja00281a051

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