Synthesis p. 674 - 676 (1986)
Update date:2022-08-04
Topics:
Brown, Herbert C.
Bhat, N. G.
Basavaiah, D.
Treatment of thexylalkenylalkynylboranes with iodine in the presence of potassium methoxide produces (E)-1,3-enynes in good yield (58-82percent) and excellent stereochemical purities (>=95percent).The methodology was successfully applied to the synthesis of (5Z,7E)-5,7-dodecadien-1-ol, the sex pheromone of the forest tent caterpillar (Malacosoma disstria).
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Doi:10.1039/jr9650001132
(1965)Doi:10.1016/j.bioorg.2020.104002
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