Tetrahedron p. 2099 - 2108 (1989)
Update date:2022-08-04
Topics:
Felluga, F.
Nitti, P.
Pitacco, G.
Valentin, E.
1,2-Oxazine N-oxide derivatives could be obtained as pure isomers from the title reagents.In methanol, they opened into the corresponding Michael-type adducts, as single double bond diastereoisomers.Hydrolyses of both the systems were also highly diastereoselective, leading to γ-diketones in the former case and to γ-nitroketones in the latter.
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