ASYMMETRIC ALDOL REACTION OF SILYL ENOL ETHERS WITH ALDEHYDES PROMOTED BY THE COMBINED USE OF CHIRAL DIAMINE COORDINATED TIN(II) TRIFLATE AND TRIBUTYLTIN FLUORIDE

DOI: 10.1246/cl.1989.297

Source and publish data:

Chemistry Letters p. 297 - 300 (1989)

Update date:2022-08-03

Topics:

Authors:

Kobayashi, Shu

Mukaiyama, Teruaki

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Article abstract of DOI:10.1246/cl.1989.297

Asymmetric aldol reaction of silyl enol ethers of thioesters with aldehydes is performed in high enantiomeric excess by the use of a new chiral promoter, a combined use of chiral diamine coordinated tin(II) triflate and tributyltin fluoride.

Full text of DOI:10.1246/cl.1989.297

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