Asymmetric Aldol Reaction between Achiral Silyl Enol Ethers and Achiral Aldehydes by Use of a Chiral Promoter System

DOI: 10.1021/ja00011a030

Source and publish data:

Journal of the American Chemical Society p. 4247 - 4252 (1991)

Update date:2022-08-03

Topics:

Authors:

Kobayashi, Shu

Uchiro, Hiromi

Fujishita, Yuko

Shiina, Isamu

Mukaiyama, Teruaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00011a030

In the presence of a chiral promoter consisting of tin(II) triflate, a chiral diamine, and tributyltin fluoride, the silyl enol ether of S-ethyl ethanethioate or S-tert-butyl ethanethioate reacts with aldehydes to afford the corresponding aldol-type adduc

Full text of DOI:10.1021/ja00011a030

Products guided by the article

Product name:(2S,3S)-S-ethyl 3-hydroxy-3-(4-methoxyphenyl)-2-methylpropanethioate

Cas No:133963-99-2

R&D Labs maybe for 133963-99-2

Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 15006126856

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province
BAODING SINO-CHEM INDUSTRY CO.,LTD

Contact:0312-5956088

Address:NO.8 FUXING ROAD,CHINA
Guangzhou Congen Pharmatec Co.,Ltd.

website:https://www.congenpharma.com

Contact:86-020-82350801

Address:Room 501, Building G11, South China Advanced Materials Innovation Park, 31 Kefeng Road, Science City, Guangzhou, China 510663
SHIJIAZHUANG CHENSHI IMPORT AND EXPORT CO.,LTD

Contact:+86-311-89871056

Address:RM2017 BUILDING CTIANSHAN GALAXY PLAZA,NO168 CHANGJIANG ROAD,GAOXIN DISTRICT,SHIJIAZHUANG CITY, HEBEI,CHINA
Kunshan Yalong Trading Co,.Ltd

Contact:86-512-57621185

Address:805-807 Room Hongqiao Mansion ,1088 West Qianjin Road, Kunshan, Jiangsu，China

Relevant to this article

Photolysis experiments on phosmet, an organophosphorus insecticide

Doi:10.1021/jf034253y
(2003)
Enantioselective reduction of prochiral ketones catalyzed by new (R)-4-(phenylmercapto)methyl-5,5-diphenyl-1,3,2-oxazaborolidine and bis[(R,R)-5,5-diphenyl-1,3,2-oxazaborolidine methyl]disulfide from L-cystine

Doi:10.1016/S0957-4166(97)00212-7
(1997)
Preparation and synthetic applications of lithiated vinyl sulfones derived from 3-buten-1-ol and 4-penten-1-ol

Doi:10.1016/S0040-4020(97)00725-4
(1997)
Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate

Doi:10.1055/s-1997-967
(1997)
X-ray structure analyses of syn/anti-conformers of N-furfuroyl-, N-benzoyl-, and N-picolinoyl-substituted (2R)-bornane-10,2-sultam derivatives

Doi:10.1002/hlca.200890153
(2008)
Synthesis and selective M-cholinoblocking activity of tetraamines. Part. I

Doi:10.1007/BF02464118
(1997)

Article Doi