Asymmetric Aldol Reaction between Achiral Silyl Enol Ethers and Achiral Aldehydes by Use of a Chiral Promoter System

DOI: 10.1021/ja00011a030

Source and publish data:

Journal of the American Chemical Society p. 4247 - 4252 (1991)

Update date:2022-08-03

Topics:

Authors:

Kobayashi, Shu

Uchiro, Hiromi

Fujishita, Yuko

Shiina, Isamu

Mukaiyama, Teruaki

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Article abstract of DOI:10.1021/ja00011a030

In the presence of a chiral promoter consisting of tin(II) triflate, a chiral diamine, and tributyltin fluoride, the silyl enol ether of S-ethyl ethanethioate or S-tert-butyl ethanethioate reacts with aldehydes to afford the corresponding aldol-type adduc

Full text of DOI:10.1021/ja00011a030

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