Asymmetric Aldol Reaction between Achiral Silyl Enol Ethers and Achiral Aldehydes by Use of a Chiral Promoter System

DOI: 10.1021/ja00011a030

Source and publish data:

Journal of the American Chemical Society p. 4247 - 4252 (1991)

Update date:2022-08-03

Topics:

Authors:

Kobayashi, Shu

Uchiro, Hiromi

Fujishita, Yuko

Shiina, Isamu

Mukaiyama, Teruaki

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00011a030

In the presence of a chiral promoter consisting of tin(II) triflate, a chiral diamine, and tributyltin fluoride, the silyl enol ether of S-ethyl ethanethioate or S-tert-butyl ethanethioate reacts with aldehydes to afford the corresponding aldol-type adduc

Full text of DOI:10.1021/ja00011a030

Products guided by the article

Product name:(2S,3S)-S-ethyl 3-hydroxy-3-(4-methoxyphenyl)-2-methylpropanethioate

Cas No:133963-99-2

R&D Labs maybe for 133963-99-2

Hangzhou GreenCo Science & Technology Co., Ltd.

Contact:86-571-88257303

Address:1713 Room,Jingui Building,Gudun Road,Xihu District,Hangzhou,China
Zhejiang Linhai Xinhua Chemicals Factory

Contact:0086-13661858911

Address:Xunqiao Development Zone, Linhai, Zhejiang, China
Jiangxi Hessence Chemicals Co., Ltd.

Contact:+86 796 3511924

Address:Chengxi Industrial Park, Jishui County, Jiangxi Province 331600 China.
KangZhiYuan Pharmaceutical Company Limited

Contact:(Sabrina)86-20-85273232

Address:4th floor, building B, Dadi industry zone, Tangxia, Tianhe, Guangzhou, China
Hubei Lansun Biochemical Pharmaceutical Co., Ltd

Contact:714-6395977

Address:No. 81 Pengcheng Avenue, economic and technological development zone, Huangshi City, Hubei Province,China

Relevant to this article

Photolysis experiments on phosmet, an organophosphorus insecticide

Doi:10.1021/jf034253y
(2003)
Enantioselective reduction of prochiral ketones catalyzed by new (R)-4-(phenylmercapto)methyl-5,5-diphenyl-1,3,2-oxazaborolidine and bis[(R,R)-5,5-diphenyl-1,3,2-oxazaborolidine methyl]disulfide from L-cystine

Doi:10.1016/S0957-4166(97)00212-7
(1997)
Preparation and synthetic applications of lithiated vinyl sulfones derived from 3-buten-1-ol and 4-penten-1-ol

Doi:10.1016/S0040-4020(97)00725-4
(1997)
Enantiospecific Synthesis of the 14-Membered Diene Unit of Methyl Sarcophytoate

Doi:10.1055/s-1997-967
(1997)
X-ray structure analyses of syn/anti-conformers of N-furfuroyl-, N-benzoyl-, and N-picolinoyl-substituted (2R)-bornane-10,2-sultam derivatives

Doi:10.1002/hlca.200890153
(2008)
Synthesis and selective M-cholinoblocking activity of tetraamines. Part. I

Doi:10.1007/BF02464118
(1997)

Article Doi