Calorimetric studies of the heats of protonation of the metal in Fe(CO)3(bidentate phosphine, arsine) complexes: Effects of chelate ligands on metal basicity

DOI: 10.1021/ja00027a023

Source and publish data:

Journal of the American Chemical Society p. 160 - 165 (1992)

Update date:2022-08-05

Topics:

Authors:

Sowa Jr., John R.

Zanotti, Valerio

Facchin, Giacomo

Angelici, Robert J.

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Article abstract of DOI:10.1021/ja00027a023

Titration calorimetry has been used to determine the beats of protonation (ΔH_HM) of Fe(CO)₃(LL) complexes (LL = dppm, dppe, dppp, dppb, dppbz, cis-dppv, arphos, dmpm, dcpe, and diars) with CF₃SO₃H in 1,2-dichlor

Full text of DOI:10.1021/ja00027a023

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Product name:{Fe(CO)3((C₆H₅)2P(CH₂)2P(C₆H₅)2)H}⁽¹⁺⁾*CF₃SO₃^(1-)={Fe(CO)3((C₆H₅)2P(CH₂)2P(C₆H₅)2)H}CF₃SO₃

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