Enantioselective reduction of benzoyl derivatives of ferrocene and ruthenocene: optically active carbinols and carbenium ions

DOI: 10.1016/0022-328X(92)80028-V

Source and publish data:

Journal of Organometallic Chemistry p. 125 - 130 (1992)

Update date:2022-08-03

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Authors:

Nefedova, Marina N.

Mamedyarova, Irina A.

Petrovski, Pavel P.

Sokolov, Viatcheslav I.

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Article abstract of DOI:10.1016/0022-328X(92)80028-V

Mono- and 1,1'-disubstituted metallocenes, XC5H4MC5H4Y, M = Fe, Ru, X = H, Y = COPh, or X = Y = COPh, have been reduced using the LiAlH4-Chirald complex to afford the corresponding carbinols and diols enantiomerically enriched.Optical yield was 53percent

Full text of DOI:10.1016/0022-328X(92)80028-V

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