Photoreactivity of Conjugated Bichromophoric Molecules; Photoreaction of o-Vinylbenzaldehyde with Secondary Amines

DOI: 10.1039/c39920000840

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 840 - 841 (1992)

Update date:2022-07-30

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Authors:

Kessar, Satinder Vir

Mankotia, Anil K. Singh

Gujral, Gurjeet

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Article abstract of DOI:10.1039/c39920000840

Irradiation of o-vinylbenzaldehyde 8 in the presence of secondary amines 9 results in N-H addition across the two chromophores to give o-ethylbenzamides 6; photolysis of o-(2-dialkylaminoethyl)benzaldehydes 5a and 5b also affords 6 via photoexpulsion followed by recombination of the 8 and 9 which are formed.

Full text of DOI:10.1039/c39920000840

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