Enantioselective, rhodium catalyzed intramolecular cyclopropanations of homoallylic diazoacetates

DOI: 10.1016/S0040-4039(00)61761-6

Source and publish data:

Tetrahedron Letters p. 6727 - 6730 (1992)

Update date:2022-08-05

Topics:

Authors:

Martin, Stephen F.

Oalmann, Christopher J.

Liras, Spiros

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61761-6

The homoallylic diazoacetates 3a-j underwent enantioselective intramolecular cyclopropanation with the rhodium catalyst Rh₂(5S-MEPY)₄ (1) to give the oxabicyclo[4.1.0]heptanes 4a-j in 71-90% enantiomeric excess and in 55-80% chemical

Full text of DOI:10.1016/S0040-4039(00)61761-6

Products guided by the article

Product name:(Z)-5-phenyl-3-pentenyl diazoacetate

Cas No:145576-40-5

R&D Labs maybe for 145576-40-5

YORK CHEMICALS LTD

Contact:+1 (647) 918 5848

Address:2343 BRIMLEY RD., Suite 250
Chengdu King-tiger Pharm-chem. Tech. Co., Ltd

Contact:028-85317716

Address:Tianfu Life Science Park, No. 88 South Keyuan Road, Gaoxin District, Chengdu City, Sichuan Province, PRC.
Shifang Taifeng New Flame Retardant Co., Ltd

Contact:02884721008

Address:tingjiang industrial park, hefeng town
Liaoyang hengye Chemical Co., Ltd.

Contact:86-419-5850866

Address:North Old Xiaoxiao Road,Yantai District, Dengta, Liaoyang, Liaoning, China
Jiangsu King Road New Materials Co., Ltd.

website:http://www.jskingroad.com

Contact:0519-85720726 0519-85720721 13584535752

Address:No.1,Weihua Road,Xinbei District,Changzhou City,Jiangsu Province

Relevant to this article

Direct introduction of ethoxycarbonyldifluoromethyl-group to heteroarenes with ethyl bromodifluoroacetate via visible-light photocatalysis

Doi:10.1002/cjoc.201300411
(2013)
Clay catalyzed highly selective O-alkylation of primary alcohols with orthoesters

Doi:10.1016/S0040-4039(97)00684-9
(1997)
Molecular docking, design, synthesis and antifungal activity study of novel triazole derivatives containing the 1,2,3-triazole group

Doi:10.1039/c3ra41310a
(2013)
3-Methylenetetrahydrofurans and 3-Methylenepyrrolidines by Addition of 2-(Bromozincmethyl)-2-alkenyl Ethers or 2-(Chloromagnesiomethyl)-2-alkenyl Ethers to Aldehydes, Ketones and Imines followed by Pd(0)-Catalyzed Cyclization

Doi:10.1016/S0040-4020(01)92280-X
(1992)
Tetrabutyl ammonium bromide-mediated benzylation of phenols in water under mild condition

Doi:10.1016/j.tet.2014.01.004
(2014)
Doi:10.1021/ja01511a045
(1959)

Article Doi