CD and 1H NMR Study of the Rotational Population Dependence of the Hydroxymethyl Group in β Glucopyranosides on the Aglycon and Its Absolute Configuration

Article abstract of DOI:10.1021/jo00113a038

The rotamer population around the C5-C6 bond of chiral and nonchiral alkyl β-glucopyranoside derivatives proved to be dependent on the structure of the aglycon; the population of the gg and gt rotamers decreased and increased, respectively, as the pK