1,9-Stereocontrol from 1,7-induction using an allylstannane followed by an Ireland-Claisen rearrangement

DOI: 10.1016/S0040-4020(98)01179-X

Source and publish data:

Tetrahedron p. 3723 - 3734 (1999)

Update date:2022-07-31

Topics:

Authors:

Moffatt, Ella-Maria

Thomas, Eric J.

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Article abstract of DOI:10.1016/S0040-4020(98)01179-X

The 6-hydroxynona-2,7-dienylstananne 10 reacts with aldehydes after transmetallation with tin(IV) bromide with syn-selective 1,7-induction (1,7- syn : 1,7-anti = ca. 90 : 10). Ireland-Claisen rearrangements of the acetates 28a,b prepared from the syn-benz

Full text of DOI:10.1016/S0040-4020(98)01179-X

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