Journal of Organic Chemistry p. 2104 - 2109 (1993)
Update date:2022-08-02
Topics:
Gross, Margaret L.
Blank, David H.
Welch, Willard M.
Reaction of (2-), (3-), and (4-bromophenyl)-3,3-(1,4-butanediyl)triazenes (derived from the corresponding 2-, 3-, and 4-bromoanilines) with sec- or tert-butyllithiums gave the corresponding (triazenylaryl)lithiums; these intermediates reacted with a variety of electrophiles to give substituted aryl triazenes.These products could be converted to substituted anilines by reduction or to novel substituted aromatics by a modified Sandmeyer reaction.
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