Tetrahedron p. 1367 - 1376 (1999)
Update date:2022-08-02
Topics: Diastereoselectivity Lactones Bicyclic Carboxylic acid Chemical Reaction Cyclopropane Formation Experimental Diastereomer Preference
Hell, Zoltan
Finta, Zoltan
Gruenvald, Tamas
Boecskei, Zsolt
Balan, Daniella
Keseru, Gyoergy M.
Toke, Laszlo
The intramolecular cyclization of malonic acid allylic esters yields bicyclic cyclopropane carboxylic acid lactones in a phase transfer catalysed reaction. The substituents of the allylic moiety and the reaction temperature influence the diastereomeric composition of the products.
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