Journal of Organometallic Chemistry p. 55 - 58 (2019)
Update date:2022-08-04
Topics:
Antonov, Artem A.
Semikolenova, Nina V.
Talsi, Evgenii P.
Bryliakov, Konstantin P.
A series of novel bis(imino)pyridine cobalt(II) chlorides, LCoCl2, with the bis(imino)pyridine ligands bearing one or several electron-withdrawing substituents (F, Cl, Br, CF3) at the aniline moieties, have been prepared and characterized. In the presence of methylalumoxane (MAO), these complexes have demonstrated high ethylene oligo- and polymerization activity (up to 1.8·107 g products?(mol Co)?1 h?1 bar?1), affording products ranging from 1-butene and Z,E-2-butenes to strictly linear low-molecular-weight (Mn ~ 300…700) polyethylene. The dependence of the reaction outcome on the ligand structure is discussed.
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