SYNTHESIS OF TRANS-4,8,12,15,15-PENTAMETHYLBICYCLOPENTADECA-3E,7Z,12Z-TRIENE, A GEOMETRICAL ISOMER OF ANHYDROVERTICILLOL

DOI: 10.1246/cl.1981.25

Source and publish data:

Chemistry Letters p. 25 - 28 (1981)

Update date:2022-08-03

Topics:

Authors:

Kumagai, Takashi

Ise, Fumiaki

Uyehara, Tadao

Kato, Tadahiro

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Article abstract of DOI:10.1246/cl.1981.25

A 7Z-isomer of anhydroverticillol skeleton was constructed in 15 percent yield when the 7E allyl bromide having secoverticillol framework was treated with LiN(TMS)2.Reductive removal of the SO2Ph group furnished a geometrical isomer of anhydroverticillol.

Full text of DOI:10.1246/cl.1981.25

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