Studies in Biomimetic Alkaloid Syntheses. 5. Total Syntheses of ψ-Vincadifformine, 20-Epi-ψ-vincadifformine, Pandoline, 20-Epipandoline and the C-16 Epimeric (Carbomethoxy)velbanamines.

DOI: 10.1021/jo01304a023

Source and publish data:

Journal of Organic Chemistry p. 3259 - 3265 (1980)

Update date:2022-08-05

Topics:

Authors:

Kuehne, Martin E.

Kirkemo, Curtis L.

Matsko, Thomas H.

Bohnert, John C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01304a023

The title racemic pentacyclic alkaloids (5b-e) were synthesized by respective reactions of the indoloazepines 8b,c with the halopentanals 10a,b or the epoxypentanal 23.Reductive opening of pandoline (5d) gave the racemic seco compounds 28a,b, and reductiv

Full text of DOI:10.1021/jo01304a023

Products guided by the article

Product name:Methyl 4-<(phenylselenyl)methyl>hexanoate

Cas No:73805-47-7

R&D Labs maybe for 73805-47-7

Tianjin Crest Pharmaceutical R&D Co., Ltd. （Tianjin Yao Technology Development Co., Ltd.）(expird)

Contact:+86-22-66211386

Address:Building B5-405, No, 80 4th Avenue, TEDA, Tianjin, China P.R. 300457
Shaanxi King Stone Enterprise Company Limited

Contact:86-29-88353805,13609285751

Address:.209 Keji Road Hi-Tech industrial Develpment Zone .Xian China
Jinan Yijialian Economic and Trade Development Co., Ltd.

Contact:+86 0531-66729596

Address:jinan
Weifang Yukai Chemical Co.,Ltd.

website:http://www.yukaichem.com/en.html

Contact:+86-536-8865336

Address:binhai economic development zone，262737 shangdong，china
Hangzhou Chemfar Ltd.

Contact:+86-571-87859231, 87859237, 87859239

Address:1606,Huarong Times Mansion, No.3880 Jiangnan Avenue, Binjiang District, Hangzhou, China, 310053

Relevant to this article

Effective Modular Iminooxazoline (IMOX) Ligands for Asymmetric Catalysis: [Zn(IMOX)]-Promoted Enantioselective Reduction of Ketones by Catecholborane

Doi:10.1002/anie.200351754
(2003)
Synthesis of Allylcarboxylic Acids from Olefins with Diethyl Oxomalonate, an Enophilic Equivalent of Carbon Dioxide

Doi:10.1021/ja00527a064
(1980)
FRONTIER ORBITAL CONTROLLED CYCLOADDITION OF 2-AZAPENTALENES

Doi:10.1016/S0040-4039(00)93619-0
(1980)
Synthesis of perhydrofuro [2,3-b] furan compounds and the structure-activity relationships of the antifeeding active compounds

Doi:10.1271/bbb1961.44.855
(1980)
Preparation and Crystal Structure of an ν-Allyl Transition Metal Tetrahydride, Tetrahydrido<1,2-bis(diphenylphosphino)ethane>(ν³-2-isopropylallyl)rhenium

Doi:10.1039/c39850000670
(1985)
Doi:10.1016/S0020-1693(00)95538-5
(1979)

Article Doi