REACTION OF THE UNSATURATED COMPLEX 5-C5Me5)2Rh2(μ-NO)(μ-CO)>BF4 WITH DIAZO COMPOUNDS

DOI: 10.1016/S0022-328X(00)86780-7

Source and publish data:

Journal of Organometallic Chemistry p. C12 - C14 (1982)

Update date:2022-08-02

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Authors:

Dimas, Peter A.

Shapley, John R.

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Article abstract of DOI:10.1016/S0022-328X(00)86780-7

The unsaturated compound <(η⁵-C5Me5)2Rh2(μ-NO)(μ-CO)>BF4, prepared from (η⁵-C5Me5)Rh(CO)2 and NOBF4, reacts with diazo reagents N2CRR' to form, after decarbonylation, the unsaturated alkylidene compounds <(η⁵-C5Me5)2Rh2(μ-

Full text of DOI:10.1016/S0022-328X(00)86780-7

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Product name:[(C₅(CH₃)5)2Rh₂(NO)(C(C₆H₅)2)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)2Rh₂(NO)(C(C₆H₅)2)]BF₄

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