DIE PHOTOCHEMISCHE UMSETZUNG VON RMn(CO)5 (R = H, C6H5, CH2C6H5) MIT 1,3-BUTADIEN UND 1,3-PENTADIEN. INSERTION VON OLEFINEN IN Mn-C-BINDUNGEN

DOI: 10.1016/S0022-328X(00)98506-1

Source and publish data:

Journal of Organometallic Chemistry p. 185 - 200 (1983)

Update date:2022-09-26

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Authors:

Lipps, Wolfgang

Kreiter, Cornelius G.

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Article abstract of DOI:10.1016/S0022-328X(00)98506-1

Irradiation of C6H5CH2Mn(CO)5 in the presence of 1,3-pentadiene gives the unstable compound cis-C6H5CH2Mn(CO)4(η²-C5H8).Thermally, the η²-C5H8 ligand is inserted into the Mn-C bond of the benzyl group and Mn(CO)4(η³-C6H10C

Full text of DOI:10.1016/S0022-328X(00)98506-1

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