Tetrahedron Letters p. 1341 - 1344 (1983)
Update date:2022-08-02
Topics:
Negishi, Ei-ichi
Chatterjee, Sugata
Addition of 2-methylcyclohexanone to 1.05 equiv of KH suspended in THF, followed by treatment with 1.25 equiv of BEt3 gives potassium enoxyborate 2a as a 90-95percent regioisomerically pure species, as judged by its 1H and 13C NMR as well as by GLC analysis of the silylated products, while the use of KN(SiMe3)2 in place of KH gives 1a as a 90-95percent pure substance.The KH-BEt3 procedure also gives 4 and 5 as 91 and 85percent regiochemically pure species, respectively.
View MoreContact:+86-28-88523492
Address:714rooms of Time Square, Pujiang County
Contact:021-36356756
Address:Room601,Building No.14,280 Yangcheng Road,Shanghai
Frapp's Chemical (NFTZ) Co.,Ltd
Contact:+86-576-86137892
Address:General Chamber of Commercial Building, 159 Wanchang Middle Road, Wenling, Zhejiang, China
Tianjin Hedong Red Cliff Chemical Reagent Factory
Contact:+86-022-84780548
Address:Li Ming Zhuang Gong Ye Yuan,Dongli District,Tianjin,China
Guangxi Bonger Pharmaceutical Co., Ltd
website:http://napo.lookchem.com/
Contact:+86-18817331185
Address:Donghai Industrial Zone, Tiandong Country,Guangxi,China
Doi:10.1246/cl.1983.1041
(1983)Doi:10.1016/j.tet.2007.03.039
(2007)Doi:10.1016/S0022-328X(00)93648-9
(1966)Doi:10.1021/jo971307s
(1997)Doi:10.1016/S0040-4039(00)81906-1
(1983)Doi:10.1021/jo0516077
(2005)
