Reduction of Cobalt(III) Complexes by Intramolecular Electron Transfer from Bound Free Radicals. A Pulse Radiolytic Study

DOI: 10.1039/DT9820000943

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 943 - 950 (1982)

Update date:2022-08-25

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Authors:

Cohen, Haim

Nutkovich, Mordchi

Meyerstein, Dan

Wieghardt, Karl

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Article abstract of DOI:10.1039/DT9820000943

The specific rates of reduction of ³⁺ by a series of nitrobenzoate and nitrogen heteroatomic anion radicals are reported.The rates of intramolecular electron transfer from the same anion radicals to a central cobalt(III) bound to them via a carboxylate group are reported, as well as for some pyrazine carboxylate anion radicals bound to the cobalt via the carboxylate and the N¹ atom.The factors affecting the rate of intramolecular electron transfer processes are discussed in detail.

Full text of DOI:10.1039/DT9820000943

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