Article abstract of DOI:10.1080/10426509708031583

The use of ultrasonic activation in Michaelis-Arbuzov reaction promote a by-product in the case of silyl derivatives and in the synthesis of methylene diphosphonate. A mechanism is proposed in which the phosphite give a nucleophilic attack on the quasiphosphonium ion in place of the halide species.

Full text of DOI:10.1080/10426509708031583

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Phosphorus, Sulfur, and Silicon and the
Related Elements
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ETUDE DE LA RÉACTION DE
MICHAELISARBUZOV SOUS ACTIVATION
ULTRASONORE
Jean-Yves Winum a , Mehrnaz Kamal a , Huguette Agnaniet a , Alain
Leydet a & Jean-Louis Montero a
a Laboratoire de Chimie Biomoléculaire Associé CNRS, Université ,
Montpellier II cc073, Place E. Bataillon, 34095, Montpellier, Cedex 5,
France
Published online: 16 Feb 2007.
To cite this article: Jean-Yves Winum , Mehrnaz Kamal , Huguette Agnaniet , Alain Leydet & Jean-
Louis Montero (1997) ETUDE DE LA RÉACTION DE MICHAELISARBUZOV SOUS ACTIVATION ULTRASONORE,
Phosphorus, Sulfur, and Silicon and the Related Elements, 129:1, 83-88, DOI: 10.1080/10426509708031583
To link to this article: http://dx.doi.org/10.1080/10426509708031583
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