Journal of Organic Chemistry p. 3097 - 3100 (1980)
Update date:2022-08-10
Topics:
Reinheimer, J. D.
Mayle, L. L.
Dolnikowski, G. G.
Gerig, J. T.
Addition of aqueous base to sulutions of 2-halo-5-nitropyridines in dimethyl sulfoxide produces a stable substance which forms 2-hydroxy-5-nitropyridine if the molar ratio of hydroxide to pyridine is greater than 2:1.IR and 1H and 13C NMR spectra of the intermediate stable substance indicate that the pyridine ring is cleaved to form this material.An SN(ANRORC) mechanism is proposed for the reaction.
View More
Wuhan Yitongtai Science and Technology Co.,Ltd.
Contact:+86-27-88933550
Address:27th Fl. Bldg. 1, Shuian International Mansion, Heping Ave, Wuhan, Hubei, China
Contact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Jiangsu Haian Petro chemical Plant
Contact:+86-513-88902723
Address:99, Changjiang West Road, Haian County, Jiangsu
Contact:86-511-85210668 0511-85210668, 85210818, 85210898
Address:Yihai Garden E-902,NO.99 Daxi RD., Zhenjiang Jiiangsu ,China
Guangzhou Flower's Song Fine Chemical CO,. Ltd
Contact:+86-20-87475199
Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Doi:10.1021/om00017a007
(1994)Doi:10.1016/j.dyepig.2011.08.013
(2012)Doi:10.1016/j.tet.2017.03.016
(2017)Doi:10.1016/j.dyepig.2017.04.012
(2017)Doi:10.1039/c39930000409
(1993)Doi:10.1016/S0008-6215(02)00481-0
(2003)
