Journal of Physical Chemistry p. 5502 - 5503 (1986)
Update date:2022-08-30
Topics:
Giround-Godquin, Anne-Marie
Marchon, Jean-Claude
Guillon, Daniel
Skoulios, Antoine
The synthesis of dirhodium tetraoctaonate and dirhodium tetradodecanoate is described.Both complexes exhibit a thermotropic discotic mesophase that was characterized by optical microscopy, differential scanning calorimetry, and X-ray diffraction.A two-dimensional hexagonal columnar lattice was observed in which each column is made of stacked metal-metal bonded dirhodium units with a period of ca. 4.6 Angstroem.
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(1925)
