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7646-78-8

Basic Information
CAS No.: 7646-78-8
Name: Tin tetrachloride
Article Data: 418
Cas Database
Molecular Structure:
Molecular Structure of 7646-78-8 (Tin tetrachloride)
Formula: Cl4Sn
Molecular Weight: 260.522
Synonyms: Tinchloride (SnCl4) (8CI);Libavius Fuming spirit;NSC 209802;Stannic chloride;Stannic tetrachloride;Tetrachlorostannane;Tetrachlorotin;Tin(IV) chloride;Tin(IV) tetrachloride;Tin Tetrachloride TTC;
EINECS: 231-588-9
Density: 2.226
Melting Point: -33 °C(lit.)
Boiling Point: 114.1 °C at 760 mmHg
Flash Point: 34°F
Solubility: Completely miscible with water
Appearance: Clear to slightly yellow fuming liquid
Hazard Symbols: CorrosiveC,ToxicT,FlammableF
Risk Codes: 34-52/53-40-23/24/25-11
Safety: 26-45-61-7/8-36/37-24/25-23-36/37/39-16
Transport Information: UN 3264 8/PG 2
PSA: 0.00000
LogP: 2.37720
Synthetic route
13445-49-3

Marshall's acid

tin(ll) chloride

A

7664-93-9

sulfuric acid

B

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
In hydrogenchloride room temp.; 10-15 min.;A n/a
B 99%
In hydrogenchloride room temp.; 10-15 min.;A n/a
B 99%

tin(IV) oxide

iron(II) chloride

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 98.97 % SnCl4 at 800°C in presence of C;;98.97%
In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 76.10 % SnCl4 at 800°C;;76.1%
In neat (no solvent) byproducts: FeO; heating of a mixture of SnO2 with double excess of FeCl2 forms 27.20 % SnCl4 at 700°C; equilibrium reaction discussed;;27.2%

tin(IV) oxide

7786-30-3

magnesium chloride

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 98.3 % SnCl4 at 800°C in presence of C;;98.3%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 74.60 % SnCl4 at 800°C;;74.6%
In neat (no solvent) byproducts: MgO; heating of a mixture of SnO2 with double excess of MgCl2 forms 58.79 % SnCl4 at 700°C; equilibrium reaction examinated;;58.79%

tin(IV) oxide

7646-85-7

zinc(II) chloride

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 97.87 % SnCl4 at 800°C in presence of C;;97.87%
In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 5.2 % SnCl4 at 800°C;;5.2%
In neat (no solvent) byproducts: ZnO; heating of a mixture of SnO2 with double excess of ZnCl2 forms 4.3 % SnCl4 at 600°C;;4.3%
117440-15-0

tetrakis-biphenyl-(2)-tin(IV)

A

10271-66-6

biphenyl-(2)-mercury(II) chloride

B

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With mercury dichloride In ethanol 20h heating in sealed tube to 120°C; absol. ethanol;;A 90.5%
B n/a
With HgCl2 In ethanol 20h heating in sealed tube to 120°C; absol. ethanol;;A 90.5%
B n/a
625-58-1

ethyl nitrate

tin(ll) chloride

A

5470-11-1

hydroxylamine hydrochloride

B

7664-41-7

ammonia

C

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With hydrogenchloride In hydrogenchloride byproducts: C2H5OH, H2O; in concd. HCl soln.; evapn. of the alcohol,diluting with water,pptg. of the Sn with H2S,evapn. and crystn. from alcohol;A 90%
B <1
C n/a
56-23-5

tetrachloromethane

595-90-4

tetraphenyltin(IV)

94-36-0

dibenzoyl peroxide

A

67-72-1

hexachloroethane

B

7646-78-8

tin(IV) chloride

C

108-90-7

chlorobenzene

D

88-99-3

benzene-1,2-dicarboxylic acid

E

65-85-0

benzoic acid

Conditions
ConditionsYield
50h boiling;A n/a
B 84.1%
C n/a
D n/a
E n/a

Tc(dimethylglyoxime)3(μ-OH)SnCl3*H2O

A

TcCl(dimethylglyoxime)3

B

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With HCl In acetonitrile room temp., 30 min. (crystn.); cooling (-20°C), decantation, washing (cold MeCN, cold 1 M HCl), drying (vac., 6 h), recrystn. (EtOH/HCl); elem. anal.;A 82%
B n/a

(R,R,S,S)-2,2',6,6'-tetra-tert-butyl-4,4'-spirobis(8-sila-4-stannatetrahydro-s-indacene)

10026-11-6

zirconium(IV) chloride

rac-dimethylsilanediylbis(t-butylcyclopentadienyl) zirconium dichloride

B

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
In toluene stirring (16 h); solvent removal (vac.), addn. pentane, filtration, volatiles rremoval (vac.);A 80%
B n/a

Tc(cyclohexanedione dioxime)3(μ-OH)SnCl3*3H2O

A

TcCl(cyclohexanedione dioxime)3

B

7646-78-8

tin(IV) chloride

Conditions
ConditionsYield
With HCl In acetonitrile stirring (30 min., pptn.); addn. of excess 1 M HCl, collection (after 15 min.), washing (1 M HCl, H2O), drying (vac.), recrystn. (MeCN/1 M HCl); elem. anal.;A 75%
B n/a
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Chemistry

Product Name: Tin tetrachloride (CAS NO.7646-78-8)

Molecular Formula: SnCl4
Molecular Weight: 260.50g/mol
Mol File: 7646-78-8.mol
EINECS: 231-588-9
Appearance: colourless liquid
Melting Point: -33 °C(lit.)
Boiling point: 114.1 °C at 760 mmHg
Storage Temperature: Store at RT.
Water Solubility: reacts
Sensitive: Air Sensitive
Stability: Stability Stable, but may decompose upon exposure to moist air or water. Incompatible with strong bases, alcohols.
Surface Tension:
Enthalpy of Vaporization: 16.15 kJ/mol
Vapour Pressure: 23.9 mmHg at 25°C
H-Bond Donor: 0
H-Bond Acceptor: 0
Structure Descriptors of Tin tetrachloride (CAS NO.7646-78-8):
  IUPAC Name: tetrachlorostannane
  Canonical SMILES: Cl[Sn](Cl)(Cl)Cl
  InChI: InChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
  InChIKey: HPGGPRDJHPYFRM-UHFFFAOYSA-J
Product Categories: Inorganics; Classes of Metal Compounds; Sn (Tin) Compounds; Typical Metal Compounds

Uses

As mordant, reviving colors, dehydrating agent in organic syntheses, stabilizer for colors & perfumes in soap, in dyeing of fabrics, weighting silk, tinning vessels, in ceramics to produce abrasion resistant or light reflecting coatings.

Toxicity Data With Reference

1.    

ihl-rat LC50:2300 mg/m3/10M

    TOXID9    Toxicologist. 1 (1981),77.
2.    

ipr-mus LD50:101 mg/kg

    COREAF    Comptes Rendus Hebdomadaires des Seances de l’Academie des Sciences. 256 (1963),1043.

Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by inhalation. A corrosive irritant to skin, eyes, and mucous membranes. Combustible by chemical reaction. Upon contact with moisture, considerable heat is generated. Violent reaction with K, Na, turpentine, ethylene oxide, alkyl nitrates. Dangerous; hydrochloric acid is liberated on contact with moisture or heat. When heated to decomposition it emits toxic fumes of Cl. See also HYDROCHLORIC ACID.
Safety Information of Tin tetrachloride (CAS NO.7646-78-8):
Hazard Codes  CCorrosive,TToxic,FFlammable
Risk Statements: 34-52/53-40-23/24/25-11  
R34:Causes burns. 
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R40:Limited evidence of a carcinogenic effect. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R11:Highly flammable.
Safety Statements: 26-45-61-7/8-36/37-24/25-23-36/37/39-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S24/25:Avoid contact with skin and eyes. 
S23:Do not breathe vapour. 
S36/37:Wear suitable protective clothing and gloves. 
S16:Keep away from sources of ignition.
RIDADR: UN 3264 8/PG 2
WGK Germany: 2
RTECS: XP8750000
F: 10-21
TSCA: Yes
HazardClass: 8
PackingGroup: II

Standards and Recommendations

OSHA PEL: TWA 2 mg(Sn)/m3
ACGIH TLV: TWA 2 mg(Sn)/m3
DOT Classification:  8; Label: Corrosive

Specification

 Tin tetrachloride , its CAS NO. is 7646-78-8, the synonyms are  Etain (tetrachlorure d') ; Libavius fuming spirit ; Stagno (tetracloruro di) ; Stannane, tetrachloro- ; Stannic chloride ; Stannic chloride, anhydrous ; Stannic tetrachloride ; Tetrachlorostannane ; Tetrachlorotin ; Tin Tetrachloride, anhydrous ; Tin chloride, fuming (DOT) ; Tin perchloride ; Tin tetrachloride ; Tin(IV) chloride ; Tin(IV) tetrachloride ; Tintetrachloride .