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7646-78-8

Basic Information
CAS No.: 7646-78-8
Name: Tin tetrachloride
Molecular Structure:
Molecular Structure of 7646-78-8 (Tin tetrachloride)
Formula: Cl4Sn
Molecular Weight: 260.50 .
Synonyms: Tinchloride (SnCl4) (8CI);Libavius Fuming spirit;NSC 209802;Stannic chloride;Stannic tetrachloride;Tetrachlorostannane;Tetrachlorotin;Tin(IV) chloride;Tin(IV) tetrachloride;Tin Tetrachloride TTC;
EINECS: 231-588-9
Density: 2.226
Melting Point: -33 °C(lit.)
Boiling Point: 114.1 °C at 760 mmHg
Flash Point: 34°F
Solubility: Completely miscible with water
Appearance: Clear to slightly yellow fuming liquid
Hazard Symbols: CorrosiveC,ToxicT,FlammableF
Risk Codes: 34-52/53-40-23/24/25-11
Safety: 26-45-61-7/8-36/37-24/25-23-36/37/39-16
Transport Information: UN 3264 8/PG 2
PSA: 0.00000
LogP: 2.37720
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Chemistry

Product Name: Tin tetrachloride (CAS NO.7646-78-8)

Molecular Formula: SnCl4
Molecular Weight: 260.50g/mol
Mol File: 7646-78-8.mol
EINECS: 231-588-9
Appearance: colourless liquid
Melting Point: -33 °C(lit.)
Boiling point: 114.1 °C at 760 mmHg
Storage Temperature: Store at RT.
Water Solubility: reacts
Sensitive: Air Sensitive
Stability: Stability Stable, but may decompose upon exposure to moist air or water. Incompatible with strong bases, alcohols.
Surface Tension:
Enthalpy of Vaporization: 16.15 kJ/mol
Vapour Pressure: 23.9 mmHg at 25°C
H-Bond Donor: 0
H-Bond Acceptor: 0
Structure Descriptors of Tin tetrachloride (CAS NO.7646-78-8):
  IUPAC Name: tetrachlorostannane
  Canonical SMILES: Cl[Sn](Cl)(Cl)Cl
  InChI: InChI=1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4
  InChIKey: HPGGPRDJHPYFRM-UHFFFAOYSA-J
Product Categories: Inorganics; Classes of Metal Compounds; Sn (Tin) Compounds; Typical Metal Compounds

Uses

As mordant, reviving colors, dehydrating agent in organic syntheses, stabilizer for colors & perfumes in soap, in dyeing of fabrics, weighting silk, tinning vessels, in ceramics to produce abrasion resistant or light reflecting coatings.

Toxicity Data With Reference

1.    

ihl-rat LC50:2300 mg/m3/10M

    TOXID9    Toxicologist. 1 (1981),77.
2.    

ipr-mus LD50:101 mg/kg

    COREAF    Comptes Rendus Hebdomadaires des Seances de l’Academie des Sciences. 256 (1963),1043.

Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

Poison by intraperitoneal route. Moderately toxic by inhalation. A corrosive irritant to skin, eyes, and mucous membranes. Combustible by chemical reaction. Upon contact with moisture, considerable heat is generated. Violent reaction with K, Na, turpentine, ethylene oxide, alkyl nitrates. Dangerous; hydrochloric acid is liberated on contact with moisture or heat. When heated to decomposition it emits toxic fumes of Cl. See also HYDROCHLORIC ACID.
Safety Information of Tin tetrachloride (CAS NO.7646-78-8):
Hazard Codes  CCorrosive,TToxic,FFlammable
Risk Statements: 34-52/53-40-23/24/25-11  
R34:Causes burns. 
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R40:Limited evidence of a carcinogenic effect. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R11:Highly flammable.
Safety Statements: 26-45-61-7/8-36/37-24/25-23-36/37/39-16
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S24/25:Avoid contact with skin and eyes. 
S23:Do not breathe vapour. 
S36/37:Wear suitable protective clothing and gloves. 
S16:Keep away from sources of ignition.
RIDADR: UN 3264 8/PG 2
WGK Germany: 2
RTECS: XP8750000
F: 10-21
TSCA: Yes
HazardClass: 8
PackingGroup: II

Standards and Recommendations

OSHA PEL: TWA 2 mg(Sn)/m3
ACGIH TLV: TWA 2 mg(Sn)/m3
DOT Classification:  8; Label: Corrosive

Specification

 Tin tetrachloride , its CAS NO. is 7646-78-8, the synonyms are  Etain (tetrachlorure d') ; Libavius fuming spirit ; Stagno (tetracloruro di) ; Stannane, tetrachloro- ; Stannic chloride ; Stannic chloride, anhydrous ; Stannic tetrachloride ; Tetrachlorostannane ; Tetrachlorotin ; Tin Tetrachloride, anhydrous ; Tin chloride, fuming (DOT) ; Tin perchloride ; Tin tetrachloride ; Tin(IV) chloride ; Tin(IV) tetrachloride ; Tintetrachloride .