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Cas Database

98-88-4

98-88-4

Identification

  • Product Name:Benzoyl chloride

  • CAS Number: 98-88-4

  • EINECS:202-710-8

  • Molecular Weight:140.569

  • Molecular Formula: C7H5ClO

  • HS Code:2916.32

  • Mol File:98-88-4.mol

Synonyms:alpha-Chlorobenzaldehyde;Benzaldehyde, alpha-chloro-;Benzoyl chloride [UN1736] [Corrosive];Benzenecarbonyl chloride;4-09-00-00721 (Beilstein Handbook Reference);Benzoic acid, chloride;cyclohexanecarbonyl chloride;1,4-Dibromobutane;benzoyl chloride;alpha-chloroBenzaldehyde; benzenecarbonyl chloride;Benzoylchloride;

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Safety information and MSDS view more

  • Pictogram(s):CorrosiveC

  • Hazard Codes:C

  • Signal Word:Danger

  • Hazard Statement:H302 Harmful if swallowedH312 Harmful in contact with skin H314 Causes severe skin burns and eye damage H317 May cause an allergic skin reaction H332 Harmful if inhaled

  • First-aid measures: General adviceConsult a physician. Show this safety data sheet to the doctor in attendance.If inhaled Fresh air, rest. Half-upright position. Artificial respiration may be needed. Refer for medical attention. See Notes. In case of skin contact Remove contaminated clothes. Rinse skin with plenty of water or shower. Refer for medical attention . Wear protective gloves when administering first aid. In case of eye contact First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention. If swallowed Rinse mouth. Rest. Do NOT induce vomiting. Refer for medical attention . INHALATION: may irritate eyes, nose and throat. INGESTION: causes acute discomfort. SKIN: causes irritation and burning. (USCG, 1999) Basic Treatment: Establish a patent airway. Suction if necessary. Encourage patient to take deep breaths. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mL/kg up to 200 mL of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . /Irritating materials/

  • Fire-fighting measures: Suitable extinguishing media Use foam, carbon dioxide, dry chemical and water fog. /Do not use/ water spray. Do not allow water to enter container. Special Hazards of Combustion Products: Highly poisonous phosgene gas may be formed in fires. Behavior in Fire: At fire temperatures the compound may react violently with water or steam. (USCG, 1999) Wear self-contained breathing apparatus for firefighting if necessary.

  • Accidental release measures: Use personal protective equipment. Avoid dust formation. Avoid breathing vapours, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust. For personal protection see section 8. Personal protection: chemical protection suit including self-contained breathing apparatus. Collect leaking liquid in sealable containers. Absorb remaining liquid in sand or inert absorbent. Then store and dispose of according to local regulations. Do NOT wash away into sewer. Neutralizing agents for acids and caustics: soda ash and water: lime.

  • Handling and storage: Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Avoid exposure - obtain special instructions before use.Provide appropriate exhaust ventilation at places where dust is formed. For precautions see section 2.2. See Chemical Dangers. Separated from food and feedstuffs and incompatible materials. Dry. Well closed.Store in a cool, dry, well-ventilated location. Outside or detached storage is preferred. Store away from oxidizing materials.

  • Exposure controls/personal protection:Occupational Exposure limit valuesBiological limit values Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. Eye/face protection Safety glasses with side-shields conforming to EN166. Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Skin protection Wear impervious clothing. The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace. Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique(without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands. The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it. Respiratory protection Wear dust mask when handling large quantities. Thermal hazards

Supplier and reference price view more

  • Manufacture/Brand
  • Product Description
  • Packaging
  • Price
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  • Purchase
  • Manufacture/Brand:TRC
  • Product Description:Benzoyl chloride
  • Packaging:1000ml
  • Price:$ 180
  • Delivery:In stock
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  • Manufacture/Brand:TRC
  • Product Description:Benzoyl chloride
  • Packaging:500ml
  • Price:$ 130
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:Benzoyl Chloride >98.0%(GC)(T)
  • Packaging:500mL
  • Price:$ 24
  • Delivery:In stock
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  • Manufacture/Brand:TCI Chemical
  • Product Description:Benzoyl Chloride >98.0%(GC)(T)
  • Packaging:25mL
  • Price:$ 19
  • Delivery:In stock
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:Benzoyl chloride 99%
  • Packaging:250 g
  • Price:$ 88
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:Benzoyl chloride 99%
  • Packaging:5 kg
  • Price:$ 256
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  • Manufacture/Brand:SynQuest Laboratories
  • Product Description:Benzoyl chloride 99%
  • Packaging:1 kg
  • Price:$ 120
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Benzoyl chloride ReagentPlus , ≥99%
  • Packaging:2.5l
  • Price:$ 147
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Benzoyl chloride ReagentPlus , ≥99%
  • Packaging:4l
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  • Manufacture/Brand:Sigma-Aldrich
  • Product Description:Benzoyl chloride ACS reagent, 99%
  • Packaging:250ml
  • Price:$ 129
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Relevant articles and documentsAll total 243 Articles be found

Remarkably Efficient Iridium Catalysts for Directed C(sp2)-H and C(sp3)-H Borylation of Diverse Classes of Substrates

Chattopadhyay, Buddhadeb,Hassan, Mirja Md Mahamudul,Hoque, Md Emdadul

supporting information, p. 5022 - 5037 (2021/05/04)

Here we describe the discovery of a new class of C-H borylation catalysts and their use for regioselective C-H borylation of aromatic, heteroaromatic, and aliphatic systems. The new catalysts have Ir-C(thienyl) or Ir-C(furyl) anionic ligands instead of the diamine-type neutral chelating ligands used in the standard C-H borylation conditions. It is reported that the employment of these newly discovered catalysts show excellent reactivity and ortho-selectivity for diverse classes of aromatic substrates with high isolated yields. Moreover, the catalysts proved to be efficient for a wide number of aliphatic substrates for selective C(sp3)-H bond borylations. Heterocyclic molecules are selectively borylated using the inherently elevated reactivity of the C-H bonds. A number of late-stage C-H functionalization have been described using the same catalysts. Furthermore, we show that one of the catalysts could be used even in open air for the C(sp2)-H and C(sp3)-H borylations enabling the method more general. Preliminary mechanistic studies suggest that the active catalytic intermediate is the Ir(bis)boryl complex, and the attached ligand acts as bidentate ligand. Collectively, this study underlines the discovery of new class of C-H borylation catalysts that should find wide application in the context of C-H functionalization chemistry.

Butyrylcholine esterase selective inhibitor as well as preparation method and application thereof

-

Paragraph 0035; 0039-0040, (2021/06/22)

The invention discloses a butyrylcholine esterase selective inhibitor as well as a preparation method and application thereof. The inhibitor is a compound shown as a formula (I). The invention also discloses application of the compound in preparation of d

One-step Conversion of Amides and Esters to Acid Chlorides with PCl3

Li, Fangshao,Wu, Xiaofang,Guo, Fengzhe,Tang, Zi-Long,Xiao, Jing

supporting information, p. 4314 - 4317 (2021/07/16)

A general and efficient iodine-promoted chlorination of amides and esters with phosphorus trichloride is described. For the first time. Various inactivated amides including secondary and tertiary amides were directly converted to the corresponding acid chlorides in one-step. The substrate scope of methyl esters including aromatic and aliphatic esters was also explored under this system. This method is simple, scalable and wide in scope, which provides an approach to preparation of these acid chlorides.

Process route upstream and downstream products

Process route

4-methoxybenzoic acid
100-09-4

4-methoxybenzoic acid

benzoyl chloride
98-88-4

benzoyl chloride

4-methoxy-benzoyl chloride
100-07-2

4-methoxy-benzoyl chloride

Conditions
Conditions Yield
With Benzotrichlorid; iron(III) chloride; In benzene; at 55 ℃; Product distribution; Rate constant; Thermodynamic data; ΔE(excit.), var. temp.;
thionyl chloride
7719-09-7

thionyl chloride

benzyl alcohol
100-51-6,185532-71-2

benzyl alcohol

benzyl chloride
100-44-7

benzyl chloride

benzoyl chloride
98-88-4

benzoyl chloride

Conditions
Conditions Yield
at 180 ℃;
chloro-nitro-phenyl-acetic acid amide
861560-61-4

chloro-nitro-phenyl-acetic acid amide

benzoyl cyanide
613-90-1

benzoyl cyanide

benzoyl chloride
98-88-4

benzoyl chloride

Benzoylformic acid
611-73-4

Benzoylformic acid

benzoic acid
65-85-0,8013-63-6

benzoic acid

Conditions
Conditions Yield
at 140 ℃;
3-methylamino-1-phenylpropan-1-ol
42142-52-9

3-methylamino-1-phenylpropan-1-ol

benzaldehyde
100-52-7

benzaldehyde

benzoyl chloride
98-88-4

benzoyl chloride

acetophenone
98-86-2

acetophenone

Phenyl vinyl ketone
768-03-6,26742-84-7

Phenyl vinyl ketone

Conditions
Conditions Yield
With tetrachloromethane; at 100 ℃;
Benzotrichlorid
98-07-7

Benzotrichlorid

N-benzoylbenzamide
614-28-8

N-benzoylbenzamide

benzoyl chloride
98-88-4

benzoyl chloride

benzonitrile
100-47-0

benzonitrile

benzoic acid
65-85-0,8013-63-6

benzoic acid

Conditions
Conditions Yield
at 140 ℃;
N-(chlorophenylmethylene)benzamide
25250-38-8

N-(chlorophenylmethylene)benzamide

N-benzoylbenzamide
614-28-8

N-benzoylbenzamide

benzoyl chloride
98-88-4

benzoyl chloride

Conditions
Conditions Yield
beim Aufbewahren;
benzyl chloride
100-44-7

benzyl chloride

benzaldehyde
100-52-7

benzaldehyde

benzoyl chloride
98-88-4

benzoyl chloride

benzoic acid
65-85-0,8013-63-6

benzoic acid

Conditions
Conditions Yield
at 160 ℃;
benzylidene dichloride
98-87-3

benzylidene dichloride

benzaldehyde
100-52-7

benzaldehyde

benzoyl chloride
98-88-4

benzoyl chloride

benzoic acid
65-85-0,8013-63-6

benzoic acid

Conditions
Conditions Yield
tetrachloromethane
56-23-5

tetrachloromethane

benzoin monomethyl ether
3524-62-7

benzoin monomethyl ether

hexachloroethane
67-72-1

hexachloroethane

1-methoxy-1-phenyl-2,2,2-trichloroethane
27904-70-7

1-methoxy-1-phenyl-2,2,2-trichloroethane

2,2,2-trichloroacetophenone
2902-69-4

2,2,2-trichloroacetophenone

1,2-diphenyl-1,2-dimethoxy ethane, meso
3962-43-4

1,2-diphenyl-1,2-dimethoxy ethane, meso

benzaldehyde
100-52-7

benzaldehyde

benzoyl chloride
98-88-4

benzoyl chloride

Conditions
Conditions Yield
Mechanism; Quantum yield; Ambient temperature; Irradiation;
94 % Chromat.
41 % Chromat.
28 % Chromat.
7 % Chromat.
48 % Chromat.
benzoic acid methyl ester
93-58-3,5705-52-2,80226-58-0

benzoic acid methyl ester

chloromethyl benzoate
5335-05-7

chloromethyl benzoate

benzoyl chloride
98-88-4

benzoyl chloride

Conditions
Conditions Yield
With tetrachloromethane; at 250 ℃; for 7h; Inert atmosphere; Autoclave;
28 %Spectr.
26 %Spectr.

Global suppliers and manufacturers

Global( 178) Suppliers
  • Company Name
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  • Hangzhou Dingyan Chem Co., Ltd
  • Business Type:Manufacturers
  • Contact Tel:86-571-86465881,86-571-87157530,86-571-88025800
  • Emails:sales@dingyanchem.com
  • Main Products:95
  • Country:China (Mainland)
  • Simagchem Corporation
  • Business Type:Manufacturers
  • Contact Tel:+86-592-2680277
  • Emails:sale@simagchem.com
  • Main Products:110
  • Country:China (Mainland)
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